[2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate

In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa­hedral defined by two phenolate O atoms and four N atoms from the hexa­dentate ligand. An intra­molecular bifurcated N—H⋯(N,O) hydrog...

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Detalles Bibliográficos
Autores principales: Liu, Ming, Mao, Jia-Wei, Pan, Zhi-Quan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379195/
https://www.ncbi.nlm.nih.gov/pubmed/22719393
http://dx.doi.org/10.1107/S1600536812024191
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author Liu, Ming
Mao, Jia-Wei
Pan, Zhi-Quan
author_facet Liu, Ming
Mao, Jia-Wei
Pan, Zhi-Quan
author_sort Liu, Ming
collection PubMed
description In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa­hedral defined by two phenolate O atoms and four N atoms from the hexa­dentate ligand. An intra­molecular bifurcated N—H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol­ecule. In the crystal, the components are connected by O—H⋯O and C—H⋯O hydrogen bonds.
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spelling pubmed-33791952012-06-20 [2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate Liu, Ming Mao, Jia-Wei Pan, Zhi-Quan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa­hedral defined by two phenolate O atoms and four N atoms from the hexa­dentate ligand. An intra­molecular bifurcated N—H⋯(N,O) hydrogen bond helps to establish the conformation of the complex mol­ecule. In the crystal, the components are connected by O—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379195/ /pubmed/22719393 http://dx.doi.org/10.1107/S1600536812024191 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ming
Mao, Jia-Wei
Pan, Zhi-Quan
[2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate
title [2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate
title_full [2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate
title_fullStr [2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate
title_full_unstemmed [2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate
title_short [2-({Benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(II) perchlorate methanol disolvate
title_sort [2-({benz­yl[2-(benz­yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth­yl)imino­meth­yl]benz­yl}amino)­eth­yl]aza­nium­yl}meth­yl)-4-methyl-6-[(pyridin-2-ylmeth­yl)imino­meth­yl]phenolato]nickel(ii) perchlorate methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379195/
https://www.ncbi.nlm.nih.gov/pubmed/22719393
http://dx.doi.org/10.1107/S1600536812024191
work_keys_str_mv AT liuming 2benzyl2benzyl5methyl2oxido3pyridin2ylmethyliminomethylbenzylaminoethylazaniumylmethyl4methyl6pyridin2ylmethyliminomethylphenolatonickeliiperchloratemethanoldisolvate
AT maojiawei 2benzyl2benzyl5methyl2oxido3pyridin2ylmethyliminomethylbenzylaminoethylazaniumylmethyl4methyl6pyridin2ylmethyliminomethylphenolatonickeliiperchloratemethanoldisolvate
AT panzhiquan 2benzyl2benzyl5methyl2oxido3pyridin2ylmethyliminomethylbenzylaminoethylazaniumylmethyl4methyl6pyridin2ylmethyliminomethylphenolatonickeliiperchloratemethanoldisolvate

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