(5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate

In the title compound, C(17)H(19)NO(2)S(2), the 2H-chromene ring system is almost planar, with a maximum deviation of 0.044 (2) Å, and the pyrrolidine ring adopts an envelope conformation. The dihedral angle between the 2H-chromene system and the planar part of the pyrrolidine ring is 83.65 (8)°. A...

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Autores principales: Mahabaleshwaraiah, N. M., Kumar, K. Mahesh, Kotresh, O., Al-eryani, Waleed Fadl Ali, Devarajegowda, H. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379197/
https://www.ncbi.nlm.nih.gov/pubmed/22719395
http://dx.doi.org/10.1107/S1600536812018004
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author Mahabaleshwaraiah, N. M.
Kumar, K. Mahesh
Kotresh, O.
Al-eryani, Waleed Fadl Ali
Devarajegowda, H. C.
author_facet Mahabaleshwaraiah, N. M.
Kumar, K. Mahesh
Kotresh, O.
Al-eryani, Waleed Fadl Ali
Devarajegowda, H. C.
author_sort Mahabaleshwaraiah, N. M.
collection PubMed
description In the title compound, C(17)H(19)NO(2)S(2), the 2H-chromene ring system is almost planar, with a maximum deviation of 0.044 (2) Å, and the pyrrolidine ring adopts an envelope conformation. The dihedral angle between the 2H-chromene system and the planar part of the pyrrolidine ring is 83.65 (8)°. A weak intra­molecular C—H⋯S hydrogen bond occurs. The crystal structure features C—H⋯O hydrogen bonds and π–π inter­actions, with a centroid–centroid distance of 3.5728 (16) Å.
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spelling pubmed-33791972012-06-20 (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate Mahabaleshwaraiah, N. M. Kumar, K. Mahesh Kotresh, O. Al-eryani, Waleed Fadl Ali Devarajegowda, H. C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(19)NO(2)S(2), the 2H-chromene ring system is almost planar, with a maximum deviation of 0.044 (2) Å, and the pyrrolidine ring adopts an envelope conformation. The dihedral angle between the 2H-chromene system and the planar part of the pyrrolidine ring is 83.65 (8)°. A weak intra­molecular C—H⋯S hydrogen bond occurs. The crystal structure features C—H⋯O hydrogen bonds and π–π inter­actions, with a centroid–centroid distance of 3.5728 (16) Å. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379197/ /pubmed/22719395 http://dx.doi.org/10.1107/S1600536812018004 Text en © Mahabaleshwaraiah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mahabaleshwaraiah, N. M.
Kumar, K. Mahesh
Kotresh, O.
Al-eryani, Waleed Fadl Ali
Devarajegowda, H. C.
(5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_full (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_fullStr (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_full_unstemmed (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_short (5,7-Dimethyl-2-oxo-2H-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
title_sort (5,7-dimethyl-2-oxo-2h-chromen-4-yl)methyl pyrrolidine-1-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379197/
https://www.ncbi.nlm.nih.gov/pubmed/22719395
http://dx.doi.org/10.1107/S1600536812018004
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