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12α-Hy­droxy-3,27-dioxooleanano-28,13-lactone

There are two independent mol­ecules in the asymmetric unit of the title compound, C(30)H(44)O(5). They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent mol­ecules the D rings adopt a sl...

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Detalles Bibliográficos
Autores principales: Hu, Jun-yi, Wu, Gang-gang, Xu, Ying-qian, Xiao, Guo-yong, Lei, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379199/
https://www.ncbi.nlm.nih.gov/pubmed/22719397
http://dx.doi.org/10.1107/S1600536812017783
Descripción
Sumario:There are two independent mol­ecules in the asymmetric unit of the title compound, C(30)H(44)O(5). They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent mol­ecules the D rings adopt a slightly distorted half-chair conformation due the presence of the lactone ring while the other four six-membered rings all adopt chair conformations. The characteristic carbon–carbon double bond of the oleanoic skeleton is absent. Inter­molecular O—H⋯O hydrogen bonds between the hy­droxy and carbonyl groups occur in the crystal structure.