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12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
There are two independent molecules in the asymmetric unit of the title compound, C(30)H(44)O(5). They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent molecules the D rings adopt a sl...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379199/ https://www.ncbi.nlm.nih.gov/pubmed/22719397 http://dx.doi.org/10.1107/S1600536812017783 |
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author | Hu, Jun-yi Wu, Gang-gang Xu, Ying-qian Xiao, Guo-yong Lei, Peng |
author_facet | Hu, Jun-yi Wu, Gang-gang Xu, Ying-qian Xiao, Guo-yong Lei, Peng |
author_sort | Hu, Jun-yi |
collection | PubMed |
description | There are two independent molecules in the asymmetric unit of the title compound, C(30)H(44)O(5). They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent molecules the D rings adopt a slightly distorted half-chair conformation due the presence of the lactone ring while the other four six-membered rings all adopt chair conformations. The characteristic carbon–carbon double bond of the oleanoic skeleton is absent. Intermolecular O—H⋯O hydrogen bonds between the hydroxy and carbonyl groups occur in the crystal structure. |
format | Online Article Text |
id | pubmed-3379199 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33791992012-06-20 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone Hu, Jun-yi Wu, Gang-gang Xu, Ying-qian Xiao, Guo-yong Lei, Peng Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(30)H(44)O(5). They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent molecules the D rings adopt a slightly distorted half-chair conformation due the presence of the lactone ring while the other four six-membered rings all adopt chair conformations. The characteristic carbon–carbon double bond of the oleanoic skeleton is absent. Intermolecular O—H⋯O hydrogen bonds between the hydroxy and carbonyl groups occur in the crystal structure. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379199/ /pubmed/22719397 http://dx.doi.org/10.1107/S1600536812017783 Text en © Hu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hu, Jun-yi Wu, Gang-gang Xu, Ying-qian Xiao, Guo-yong Lei, Peng 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone |
title | 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone |
title_full | 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone |
title_fullStr | 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone |
title_full_unstemmed | 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone |
title_short | 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone |
title_sort | 12α-hydroxy-3,27-dioxooleanano-28,13-lactone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379199/ https://www.ncbi.nlm.nih.gov/pubmed/22719397 http://dx.doi.org/10.1107/S1600536812017783 |
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