Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate

The title compound, C(29)H(33)NO(8), is a product of the Michael addition of the cyclic secondary amine subunit of the aza-14-crown-4 ether to dimethyl acetyl­enedicarboxyl­ate. The piperidinone ring exhibits a distorted chair conformation, and the dimethyl ethylenedicarboxylate fragment has a cis c...

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Autores principales: Anh, Le Tuan, Hieu, Truong Hong, Soldatenkov, Anatoly T., Kolyadina, Nadezhda M., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379201/
https://www.ncbi.nlm.nih.gov/pubmed/22719399
http://dx.doi.org/10.1107/S1600536812018867
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author Anh, Le Tuan
Hieu, Truong Hong
Soldatenkov, Anatoly T.
Kolyadina, Nadezhda M.
Khrustalev, Victor N.
author_facet Anh, Le Tuan
Hieu, Truong Hong
Soldatenkov, Anatoly T.
Kolyadina, Nadezhda M.
Khrustalev, Victor N.
author_sort Anh, Le Tuan
collection PubMed
description The title compound, C(29)H(33)NO(8), is a product of the Michael addition of the cyclic secondary amine subunit of the aza-14-crown-4 ether to dimethyl acetyl­enedicarboxyl­ate. The piperidinone ring exhibits a distorted chair conformation, and the dimethyl ethylenedicarboxylate fragment has a cis configuration with a dihedral angle of 78.96 (5)° between the two carboxyl­ate groups. The crystal packing is stabilized by weak C—H⋯O hydrogen bonds.
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spelling pubmed-33792012012-06-20 Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate Anh, Le Tuan Hieu, Truong Hong Soldatenkov, Anatoly T. Kolyadina, Nadezhda M. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(29)H(33)NO(8), is a product of the Michael addition of the cyclic secondary amine subunit of the aza-14-crown-4 ether to dimethyl acetyl­enedicarboxyl­ate. The piperidinone ring exhibits a distorted chair conformation, and the dimethyl ethylenedicarboxylate fragment has a cis configuration with a dihedral angle of 78.96 (5)° between the two carboxyl­ate groups. The crystal packing is stabilized by weak C—H⋯O hydrogen bonds. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379201/ /pubmed/22719399 http://dx.doi.org/10.1107/S1600536812018867 Text en © Anh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anh, Le Tuan
Hieu, Truong Hong
Soldatenkov, Anatoly T.
Kolyadina, Nadezhda M.
Khrustalev, Victor N.
Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
title Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
title_full Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
title_fullStr Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
title_full_unstemmed Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
title_short Dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
title_sort dimethyl 2-[22,24-dimethyl-23-oxo-8,11,14-trioxa-25-aza­tetra­cyclo­[19.3.1.0(2,7).0(15,20)]penta­cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379201/
https://www.ncbi.nlm.nih.gov/pubmed/22719399
http://dx.doi.org/10.1107/S1600536812018867
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