N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate

In the title compound, C(21)H(18)N(6)·H(2)O, two 4,4′-dipyridyl­amine groups are linked by a methyl­ene C atom, which sits on a twofold axis. The lattice water mol­ecule is located slightly off a twofold axis, and is therefore disordered over two positions. In the crystal, the organic mol­ecules and...

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Detalles Bibliográficos
Autores principales: Shin, Jong Won, Min, Kil Sik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379210/
https://www.ncbi.nlm.nih.gov/pubmed/22719408
http://dx.doi.org/10.1107/S1600536812019010
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author Shin, Jong Won
Min, Kil Sik
author_facet Shin, Jong Won
Min, Kil Sik
author_sort Shin, Jong Won
collection PubMed
description In the title compound, C(21)H(18)N(6)·H(2)O, two 4,4′-dipyridyl­amine groups are linked by a methyl­ene C atom, which sits on a twofold axis. The lattice water mol­ecule is located slightly off a twofold axis, and is therefore disordered over two positions. In the crystal, the organic mol­ecules and the water mol­ecule are linked by O—H⋯N hydrogen bonds. The organic mol­ecules exhibit extensive offset face-to-face π–π inter­actions to symmetry equivalents [centroid–centroid distances = 3.725 (3) and 4.059 (3) Å].
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spelling pubmed-33792102012-06-20 N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate Shin, Jong Won Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(18)N(6)·H(2)O, two 4,4′-dipyridyl­amine groups are linked by a methyl­ene C atom, which sits on a twofold axis. The lattice water mol­ecule is located slightly off a twofold axis, and is therefore disordered over two positions. In the crystal, the organic mol­ecules and the water mol­ecule are linked by O—H⋯N hydrogen bonds. The organic mol­ecules exhibit extensive offset face-to-face π–π inter­actions to symmetry equivalents [centroid–centroid distances = 3.725 (3) and 4.059 (3) Å]. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379210/ /pubmed/22719408 http://dx.doi.org/10.1107/S1600536812019010 Text en © Shin and Min 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shin, Jong Won
Min, Kil Sik
N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate
title N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate
title_full N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate
title_fullStr N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate
title_full_unstemmed N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate
title_short N,N,N′,N′-Tetra­kis(pyridin-4-yl)methane­diamine monohydrate
title_sort n,n,n′,n′-tetra­kis(pyridin-4-yl)methane­diamine monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379210/
https://www.ncbi.nlm.nih.gov/pubmed/22719408
http://dx.doi.org/10.1107/S1600536812019010
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