Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate

The title solvated ester, C(22)H(29)NO(3)S·0.5C(6)H(14), crystallizes with two independent mol­ecules along with a hexane mol­ecule in the asymmetric unit. The two aromatic rings are separated by an –CH(2)–S– linkage; the rings are aligned at 83.27 (4)° in one mol­ecule and 47.66 (7)° in the other....

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Detalles Bibliográficos
Autores principales: Ariffin, Azhar, Nordin, Nordiana, Yehye, Wagee A., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379213/
https://www.ncbi.nlm.nih.gov/pubmed/22719411
http://dx.doi.org/10.1107/S1600536812018739
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author Ariffin, Azhar
Nordin, Nordiana
Yehye, Wagee A.
Ng, Seik Weng
author_facet Ariffin, Azhar
Nordin, Nordiana
Yehye, Wagee A.
Ng, Seik Weng
author_sort Ariffin, Azhar
collection PubMed
description The title solvated ester, C(22)H(29)NO(3)S·0.5C(6)H(14), crystallizes with two independent mol­ecules along with a hexane mol­ecule in the asymmetric unit. The two aromatic rings are separated by an –CH(2)–S– linkage; the rings are aligned at 83.27 (4)° in one mol­ecule and 47.66 (7)° in the other. The hy­droxy group of one mol­ecule forms an O—H⋯O hydrogen bond to the other mol­ecule.
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spelling pubmed-33792132012-06-20 Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate Ariffin, Azhar Nordin, Nordiana Yehye, Wagee A. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title solvated ester, C(22)H(29)NO(3)S·0.5C(6)H(14), crystallizes with two independent mol­ecules along with a hexane mol­ecule in the asymmetric unit. The two aromatic rings are separated by an –CH(2)–S– linkage; the rings are aligned at 83.27 (4)° in one mol­ecule and 47.66 (7)° in the other. The hy­droxy group of one mol­ecule forms an O—H⋯O hydrogen bond to the other mol­ecule. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379213/ /pubmed/22719411 http://dx.doi.org/10.1107/S1600536812018739 Text en © Ariffin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ariffin, Azhar
Nordin, Nordiana
Yehye, Wagee A.
Ng, Seik Weng
Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
title Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
title_full Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
title_fullStr Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
title_full_unstemmed Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
title_short Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
title_sort methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379213/
https://www.ncbi.nlm.nih.gov/pubmed/22719411
http://dx.doi.org/10.1107/S1600536812018739
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AT yehyewageea methyl235ditertbutyl4hydroxybenzylsulfanylpyridine3carboxylatenhexanehemisolvate
AT ngseikweng methyl235ditertbutyl4hydroxybenzylsulfanylpyridine3carboxylatenhexanehemisolvate

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