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9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one

The cyclo­hexene ring that constitutes a part of the tetra­hydroxanthene fused-ring system of the title compound, C(23)H(26)O(4), adopts a flattened half-chair conformation that approximates an envelope conformation (in which the methyl­ene C atom bearing the two methyl substituents represents the f...

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Autores principales: Kurbanova, Malahat M., Gurbanov, Atash V., Mahmudov, Kamran T., Maharramov, Abel M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379214/
https://www.ncbi.nlm.nih.gov/pubmed/22719412
http://dx.doi.org/10.1107/S1600536812018934
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author Kurbanova, Malahat M.
Gurbanov, Atash V.
Mahmudov, Kamran T.
Maharramov, Abel M.
Ng, Seik Weng
author_facet Kurbanova, Malahat M.
Gurbanov, Atash V.
Mahmudov, Kamran T.
Maharramov, Abel M.
Ng, Seik Weng
author_sort Kurbanova, Malahat M.
collection PubMed
description The cyclo­hexene ring that constitutes a part of the tetra­hydroxanthene fused-ring system of the title compound, C(23)H(26)O(4), adopts a flattened half-chair conformation that approximates an envelope conformation (in which the methyl­ene C atom bearing the two methyl substituents represents the flap) as five of the six atoms lie approximately on a plane (r.m.s. deviation = 0.020 Å). The mean plane of the cyclo­hexene ring with the hy­droxy substituent is approximately perpendicular to the mean plane of the tetra­hydroxanthene system. In the crystal, adjacent mol­ecules are linked by O—H⋯O(carbon­yl) hydrogen bonds into a chain running along the b axis.
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spelling pubmed-33792142012-06-20 9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one Kurbanova, Malahat M. Gurbanov, Atash V. Mahmudov, Kamran T. Maharramov, Abel M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The cyclo­hexene ring that constitutes a part of the tetra­hydroxanthene fused-ring system of the title compound, C(23)H(26)O(4), adopts a flattened half-chair conformation that approximates an envelope conformation (in which the methyl­ene C atom bearing the two methyl substituents represents the flap) as five of the six atoms lie approximately on a plane (r.m.s. deviation = 0.020 Å). The mean plane of the cyclo­hexene ring with the hy­droxy substituent is approximately perpendicular to the mean plane of the tetra­hydroxanthene system. In the crystal, adjacent mol­ecules are linked by O—H⋯O(carbon­yl) hydrogen bonds into a chain running along the b axis. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379214/ /pubmed/22719412 http://dx.doi.org/10.1107/S1600536812018934 Text en © Kurbanova et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kurbanova, Malahat M.
Gurbanov, Atash V.
Mahmudov, Kamran T.
Maharramov, Abel M.
Ng, Seik Weng
9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one
title 9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one
title_full 9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one
title_fullStr 9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one
title_full_unstemmed 9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one
title_short 9-(2-Hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1H-xanthen-1-one
title_sort 9-(2-hy­droxy-4,4-dimethyl-6-oxocyclo­hex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetra­hydro-1h-xanthen-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379214/
https://www.ncbi.nlm.nih.gov/pubmed/22719412
http://dx.doi.org/10.1107/S1600536812018934
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