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9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one
The cyclohexene ring that constitutes a part of the tetrahydroxanthene fused-ring system of the title compound, C(23)H(26)O(4), adopts a flattened half-chair conformation that approximates an envelope conformation (in which the methylene C atom bearing the two methyl substituents represents the f...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379214/ https://www.ncbi.nlm.nih.gov/pubmed/22719412 http://dx.doi.org/10.1107/S1600536812018934 |
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author | Kurbanova, Malahat M. Gurbanov, Atash V. Mahmudov, Kamran T. Maharramov, Abel M. Ng, Seik Weng |
author_facet | Kurbanova, Malahat M. Gurbanov, Atash V. Mahmudov, Kamran T. Maharramov, Abel M. Ng, Seik Weng |
author_sort | Kurbanova, Malahat M. |
collection | PubMed |
description | The cyclohexene ring that constitutes a part of the tetrahydroxanthene fused-ring system of the title compound, C(23)H(26)O(4), adopts a flattened half-chair conformation that approximates an envelope conformation (in which the methylene C atom bearing the two methyl substituents represents the flap) as five of the six atoms lie approximately on a plane (r.m.s. deviation = 0.020 Å). The mean plane of the cyclohexene ring with the hydroxy substituent is approximately perpendicular to the mean plane of the tetrahydroxanthene system. In the crystal, adjacent molecules are linked by O—H⋯O(carbonyl) hydrogen bonds into a chain running along the b axis. |
format | Online Article Text |
id | pubmed-3379214 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33792142012-06-20 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one Kurbanova, Malahat M. Gurbanov, Atash V. Mahmudov, Kamran T. Maharramov, Abel M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The cyclohexene ring that constitutes a part of the tetrahydroxanthene fused-ring system of the title compound, C(23)H(26)O(4), adopts a flattened half-chair conformation that approximates an envelope conformation (in which the methylene C atom bearing the two methyl substituents represents the flap) as five of the six atoms lie approximately on a plane (r.m.s. deviation = 0.020 Å). The mean plane of the cyclohexene ring with the hydroxy substituent is approximately perpendicular to the mean plane of the tetrahydroxanthene system. In the crystal, adjacent molecules are linked by O—H⋯O(carbonyl) hydrogen bonds into a chain running along the b axis. International Union of Crystallography 2012-05-02 /pmc/articles/PMC3379214/ /pubmed/22719412 http://dx.doi.org/10.1107/S1600536812018934 Text en © Kurbanova et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kurbanova, Malahat M. Gurbanov, Atash V. Mahmudov, Kamran T. Maharramov, Abel M. Ng, Seik Weng 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one |
title | 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one |
title_full | 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one |
title_fullStr | 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one |
title_full_unstemmed | 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one |
title_short | 9-(2-Hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one |
title_sort | 9-(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1h-xanthen-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379214/ https://www.ncbi.nlm.nih.gov/pubmed/22719412 http://dx.doi.org/10.1107/S1600536812018934 |
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