4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione

In the asymmetric unit of the title compound, C(10)H(9)FN(4)S, there are two independent mol­ecules in which the dihedral angles between the 1,2,4-triazole and benzene rings are 36.85 (10) and 7.81 (10)°. In the crystal, N—H⋯S inter­actions link pairs of independent mol­ecules into dimers. There are...

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Autores principales: Devarajegowda, H. C., Jeyaseelan, S., Sathishkumar, R., D’souza, Agnes Sylvia, D’souza, Alphonsus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379215/
https://www.ncbi.nlm.nih.gov/pubmed/22719413
http://dx.doi.org/10.1107/S1600536812019174
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author Devarajegowda, H. C.
Jeyaseelan, S.
Sathishkumar, R.
D’souza, Agnes Sylvia
D’souza, Alphonsus
author_facet Devarajegowda, H. C.
Jeyaseelan, S.
Sathishkumar, R.
D’souza, Agnes Sylvia
D’souza, Alphonsus
author_sort Devarajegowda, H. C.
collection PubMed
description In the asymmetric unit of the title compound, C(10)H(9)FN(4)S, there are two independent mol­ecules in which the dihedral angles between the 1,2,4-triazole and benzene rings are 36.85 (10) and 7.81 (10)°. In the crystal, N—H⋯S inter­actions link pairs of independent mol­ecules into dimers. There are also π–π inter­actions between the triazole and benzene rings of inversion-related pairs of the more planar mol­ecule [centroid–centroid distance = 3.6430 (13) Å].
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spelling pubmed-33792152012-06-20 4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione Devarajegowda, H. C. Jeyaseelan, S. Sathishkumar, R. D’souza, Agnes Sylvia D’souza, Alphonsus Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(10)H(9)FN(4)S, there are two independent mol­ecules in which the dihedral angles between the 1,2,4-triazole and benzene rings are 36.85 (10) and 7.81 (10)°. In the crystal, N—H⋯S inter­actions link pairs of independent mol­ecules into dimers. There are also π–π inter­actions between the triazole and benzene rings of inversion-related pairs of the more planar mol­ecule [centroid–centroid distance = 3.6430 (13) Å]. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379215/ /pubmed/22719413 http://dx.doi.org/10.1107/S1600536812019174 Text en © Devarajegowda et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Devarajegowda, H. C.
Jeyaseelan, S.
Sathishkumar, R.
D’souza, Agnes Sylvia
D’souza, Alphonsus
4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title 4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_full 4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_fullStr 4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_full_unstemmed 4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_short 4-[(E)-(4-Fluoro­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_sort 4-[(e)-(4-fluoro­benzyl­idene)amino]-3-methyl-1h-1,2,4-triazole-5(4h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379215/
https://www.ncbi.nlm.nih.gov/pubmed/22719413
http://dx.doi.org/10.1107/S1600536812019174
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