2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol

The title compound, C(14)H(13)NO(2), adopts the enol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond which generates an S(6) ring motif. The dihedral angle between the aromatic rings is 7.85 (7)°. The crystal structure is stabilized by O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, formin...

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Autores principales: Mohamed, Shaaban K., Abdelhamid, Antar A., Akkurt, Mehmet, Fanwick, Phillip E., Maharramov, A. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379224/
https://www.ncbi.nlm.nih.gov/pubmed/22719422
http://dx.doi.org/10.1107/S1600536812019368
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author Mohamed, Shaaban K.
Abdelhamid, Antar A.
Akkurt, Mehmet
Fanwick, Phillip E.
Maharramov, A. M.
author_facet Mohamed, Shaaban K.
Abdelhamid, Antar A.
Akkurt, Mehmet
Fanwick, Phillip E.
Maharramov, A. M.
author_sort Mohamed, Shaaban K.
collection PubMed
description The title compound, C(14)H(13)NO(2), adopts the enol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond which generates an S(6) ring motif. The dihedral angle between the aromatic rings is 7.85 (7)°. The crystal structure is stabilized by O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, forming a two-dimensional array that stacks along the a axis. In addition, a C—H⋯π inter­action contributes to the stabilization of the crystal packing.
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spelling pubmed-33792242012-06-20 2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol Mohamed, Shaaban K. Abdelhamid, Antar A. Akkurt, Mehmet Fanwick, Phillip E. Maharramov, A. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(13)NO(2), adopts the enol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond which generates an S(6) ring motif. The dihedral angle between the aromatic rings is 7.85 (7)°. The crystal structure is stabilized by O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, forming a two-dimensional array that stacks along the a axis. In addition, a C—H⋯π inter­action contributes to the stabilization of the crystal packing. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379224/ /pubmed/22719422 http://dx.doi.org/10.1107/S1600536812019368 Text en © Mohamed et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohamed, Shaaban K.
Abdelhamid, Antar A.
Akkurt, Mehmet
Fanwick, Phillip E.
Maharramov, A. M.
2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
title 2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
title_full 2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
title_fullStr 2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
title_full_unstemmed 2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
title_short 2-((E)-{[4-(Hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
title_sort 2-((e)-{[4-(hy­droxy­meth­yl)phen­yl]imino}­meth­yl)phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379224/
https://www.ncbi.nlm.nih.gov/pubmed/22719422
http://dx.doi.org/10.1107/S1600536812019368
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AT fanwickphillipe 2e4hydroxymethylphenyliminomethylphenol
AT maharramovam 2e4hydroxymethylphenyliminomethylphenol

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