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N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide
In the title hydrazonodithioate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C—N—N—C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379243/ https://www.ncbi.nlm.nih.gov/pubmed/22719441 http://dx.doi.org/10.1107/S1600536812019472 |
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author | Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. |
author_facet | Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. |
author_sort | Tayamon, Shahedeh |
collection | PubMed |
description | In the title hydrazonodithioate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C—N—N—C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supramolecular chains sustained by N—H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C—H⋯O and C—H⋯N interactions. |
format | Online Article Text |
id | pubmed-3379243 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33792432012-06-20 N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrazonodithioate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C—N—N—C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supramolecular chains sustained by N—H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C—H⋯O and C—H⋯N interactions. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379243/ /pubmed/22719441 http://dx.doi.org/10.1107/S1600536812019472 Text en © Tayamon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide |
title |
N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide |
title_full |
N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide |
title_fullStr |
N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide |
title_full_unstemmed |
N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide |
title_short |
N′-[Bis(benzylsulfanyl)methylidene]benzohydrazide |
title_sort | n′-[bis(benzylsulfanyl)methylidene]benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379243/ https://www.ncbi.nlm.nih.gov/pubmed/22719441 http://dx.doi.org/10.1107/S1600536812019472 |
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