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N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide

In the title hydrazonodithio­ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C—N—N—C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogo...

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Autores principales: Tayamon, Shahedeh, Ravoof, Thahira Begum S. A., Tahir, Mohamed Ibrahim Mohamed, Crouse, Karen A., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379243/
https://www.ncbi.nlm.nih.gov/pubmed/22719441
http://dx.doi.org/10.1107/S1600536812019472
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author Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_facet Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_sort Tayamon, Shahedeh
collection PubMed
description In the title hydrazonodithio­ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C—N—N—C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supra­molecular chains sustained by N—H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C—H⋯O and C—H⋯N inter­actions.
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spelling pubmed-33792432012-06-20 N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrazonodithio­ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C—N—N—C torsion angle is 139.71 (13)°. The pyridine ring forms dihedral angles of 52.96 (8) and 86.46 (8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42 (9)°]. Supra­molecular chains sustained by N—H⋯O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C—H⋯O and C—H⋯N inter­actions. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379243/ /pubmed/22719441 http://dx.doi.org/10.1107/S1600536812019472 Text en © Tayamon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
title N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
title_full N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
title_fullStr N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
title_full_unstemmed N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
title_short N′-[Bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
title_sort n′-[bis(benzyl­sulfan­yl)methyl­idene]benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379243/
https://www.ncbi.nlm.nih.gov/pubmed/22719441
http://dx.doi.org/10.1107/S1600536812019472
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