Cargando…
(E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine
The molecule of the title hydrazone derivative, C(14)H(11)FN(4)O(4), is nearly planar, with a dihedral angle between the benzene rings of 3.71 (7)°. The central ethylidenehydrazine N—N=C—C plane makes dihedral angles of 5.32 (10) and 9.02 (10)° with the 2,4-dinitro- and 3-fluoro-substituted benzen...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379246/ https://www.ncbi.nlm.nih.gov/pubmed/22719444 http://dx.doi.org/10.1107/S160053681201937X |
_version_ | 1782236155905835008 |
---|---|
author | Chantrapromma, Suchada Nilwanna, Boonlerd Kobkeatthawin, Thawanrat Jansrisewangwong, Patcharaporn Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Nilwanna, Boonlerd Kobkeatthawin, Thawanrat Jansrisewangwong, Patcharaporn Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | The molecule of the title hydrazone derivative, C(14)H(11)FN(4)O(4), is nearly planar, with a dihedral angle between the benzene rings of 3.71 (7)°. The central ethylidenehydrazine N—N=C—C plane makes dihedral angles of 5.32 (10) and 9.02 (10)° with the 2,4-dinitro- and 3-fluoro-substituted benzene rings, respectively. An intramolecular N—H⋯O bond generates an S(6) ring motif. In the crystal, molecules are linked by weak C—H⋯O interactions into a sheet parallel to (10-1). The molecules are further stacked along the a axis by π–π interactions with centroid–centroid distances of 3.6314 (9) and 3.7567 (10) Å. A C⋯F short contact [2.842 (3) Å] is observed. The 3-fluorophenyl group is disordered over two orientations with a site-occupancy ratio of 0.636 (3):0.364 (3). |
format | Online Article Text |
id | pubmed-3379246 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33792462012-06-20 (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine Chantrapromma, Suchada Nilwanna, Boonlerd Kobkeatthawin, Thawanrat Jansrisewangwong, Patcharaporn Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title hydrazone derivative, C(14)H(11)FN(4)O(4), is nearly planar, with a dihedral angle between the benzene rings of 3.71 (7)°. The central ethylidenehydrazine N—N=C—C plane makes dihedral angles of 5.32 (10) and 9.02 (10)° with the 2,4-dinitro- and 3-fluoro-substituted benzene rings, respectively. An intramolecular N—H⋯O bond generates an S(6) ring motif. In the crystal, molecules are linked by weak C—H⋯O interactions into a sheet parallel to (10-1). The molecules are further stacked along the a axis by π–π interactions with centroid–centroid distances of 3.6314 (9) and 3.7567 (10) Å. A C⋯F short contact [2.842 (3) Å] is observed. The 3-fluorophenyl group is disordered over two orientations with a site-occupancy ratio of 0.636 (3):0.364 (3). International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379246/ /pubmed/22719444 http://dx.doi.org/10.1107/S160053681201937X Text en © Chantrapromma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Nilwanna, Boonlerd Kobkeatthawin, Thawanrat Jansrisewangwong, Patcharaporn Fun, Hoong-Kun (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
title | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
title_full | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
title_fullStr | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
title_full_unstemmed | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
title_short | (E)-1-(2,4-Dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
title_sort | (e)-1-(2,4-dinitrophenyl)-2-[1-(3-fluorophenyl)ethylidene]hydrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379246/ https://www.ncbi.nlm.nih.gov/pubmed/22719444 http://dx.doi.org/10.1107/S160053681201937X |
work_keys_str_mv | AT chantraprommasuchada e124dinitrophenyl213fluorophenylethylidenehydrazine AT nilwannaboonlerd e124dinitrophenyl213fluorophenylethylidenehydrazine AT kobkeatthawinthawanrat e124dinitrophenyl213fluorophenylethylidenehydrazine AT jansrisewangwongpatcharaporn e124dinitrophenyl213fluorophenylethylidenehydrazine AT funhoongkun e124dinitrophenyl213fluorophenylethylidenehydrazine |