4-Acetamido­anilinium nitrate monohydrate

In the title hydrated salt, C(8)H(11)N(2)O(+)·NO(3) (−)·H(2)O, the N—C bond distances [1.349 (2) and 1.413 (2) Å] along with the sum of the angles (359.88°) around the acetamide N atom clearly indicate that the heteroatom has an sp (2) character. The ammonium group is involved in a total of three N—...

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Detalles Bibliográficos
Autores principales: Riahi, Sana, Mrad, Mohamed Lahbib, Ferretti, Valeria, Lefebvre, Frederic, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379248/
https://www.ncbi.nlm.nih.gov/pubmed/22719446
http://dx.doi.org/10.1107/S1600536812019393
Descripción
Sumario:In the title hydrated salt, C(8)H(11)N(2)O(+)·NO(3) (−)·H(2)O, the N—C bond distances [1.349 (2) and 1.413 (2) Å] along with the sum of the angles (359.88°) around the acetamide N atom clearly indicate that the heteroatom has an sp (2) character. The ammonium group is involved in a total of three N—H⋯O hydrogen bonds, two of these are with a water mol­ecule, which forms two O—H⋯O hydrogen bonds. All these hydrogen bonds link the ionic units and the water mol­ecule into infinite planar layers parallel to (100). The remaining two N—H⋯O inter­actions in which the ammoniun group is involved link these layers into an infinite three-dimensional network.

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