4-Acetamido­anilinium nitrate monohydrate

In the title hydrated salt, C(8)H(11)N(2)O(+)·NO(3) (−)·H(2)O, the N—C bond distances [1.349 (2) and 1.413 (2) Å] along with the sum of the angles (359.88°) around the acetamide N atom clearly indicate that the heteroatom has an sp (2) character. The ammonium group is involved in a total of three N—...

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Autores principales: Riahi, Sana, Mrad, Mohamed Lahbib, Ferretti, Valeria, Lefebvre, Frederic, Ben Nasr, Cherif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379248/
https://www.ncbi.nlm.nih.gov/pubmed/22719446
http://dx.doi.org/10.1107/S1600536812019393
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author Riahi, Sana
Mrad, Mohamed Lahbib
Ferretti, Valeria
Lefebvre, Frederic
Ben Nasr, Cherif
author_facet Riahi, Sana
Mrad, Mohamed Lahbib
Ferretti, Valeria
Lefebvre, Frederic
Ben Nasr, Cherif
author_sort Riahi, Sana
collection PubMed
description In the title hydrated salt, C(8)H(11)N(2)O(+)·NO(3) (−)·H(2)O, the N—C bond distances [1.349 (2) and 1.413 (2) Å] along with the sum of the angles (359.88°) around the acetamide N atom clearly indicate that the heteroatom has an sp (2) character. The ammonium group is involved in a total of three N—H⋯O hydrogen bonds, two of these are with a water mol­ecule, which forms two O—H⋯O hydrogen bonds. All these hydrogen bonds link the ionic units and the water mol­ecule into infinite planar layers parallel to (100). The remaining two N—H⋯O inter­actions in which the ammoniun group is involved link these layers into an infinite three-dimensional network.
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spelling pubmed-33792482012-06-20 4-Acetamido­anilinium nitrate monohydrate Riahi, Sana Mrad, Mohamed Lahbib Ferretti, Valeria Lefebvre, Frederic Ben Nasr, Cherif Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(8)H(11)N(2)O(+)·NO(3) (−)·H(2)O, the N—C bond distances [1.349 (2) and 1.413 (2) Å] along with the sum of the angles (359.88°) around the acetamide N atom clearly indicate that the heteroatom has an sp (2) character. The ammonium group is involved in a total of three N—H⋯O hydrogen bonds, two of these are with a water mol­ecule, which forms two O—H⋯O hydrogen bonds. All these hydrogen bonds link the ionic units and the water mol­ecule into infinite planar layers parallel to (100). The remaining two N—H⋯O inter­actions in which the ammoniun group is involved link these layers into an infinite three-dimensional network. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379248/ /pubmed/22719446 http://dx.doi.org/10.1107/S1600536812019393 Text en © Riahi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Riahi, Sana
Mrad, Mohamed Lahbib
Ferretti, Valeria
Lefebvre, Frederic
Ben Nasr, Cherif
4-Acetamido­anilinium nitrate monohydrate
title 4-Acetamido­anilinium nitrate monohydrate
title_full 4-Acetamido­anilinium nitrate monohydrate
title_fullStr 4-Acetamido­anilinium nitrate monohydrate
title_full_unstemmed 4-Acetamido­anilinium nitrate monohydrate
title_short 4-Acetamido­anilinium nitrate monohydrate
title_sort 4-acetamido­anilinium nitrate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379248/
https://www.ncbi.nlm.nih.gov/pubmed/22719446
http://dx.doi.org/10.1107/S1600536812019393
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AT ferrettivaleria 4acetamidoaniliniumnitratemonohydrate
AT lefebvrefrederic 4acetamidoaniliniumnitratemonohydrate
AT bennasrcherif 4acetamidoaniliniumnitratemonohydrate

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