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2-Cyano-1-methylpyridinium nitrate
In the title compound, C(7)H(7)N(2) (+)·NO(3) (−), all atoms except the methyl H atoms lie on a crystallographic mirror plane. The interlayer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å. Two-dimension...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379252/ https://www.ncbi.nlm.nih.gov/pubmed/22719450 http://dx.doi.org/10.1107/S1600536812019460 |
| _version_ | 1782236157284712448 |
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| author | Koplitz, Lynn V. Mague, Joel T. Kammer, Michael N. McCormick, Cameron A. Renfro, Heather E. Vumbaco, David J. |
| author_facet | Koplitz, Lynn V. Mague, Joel T. Kammer, Michael N. McCormick, Cameron A. Renfro, Heather E. Vumbaco, David J. |
| author_sort | Koplitz, Lynn V. |
| collection | PubMed |
| description | In the title compound, C(7)H(7)N(2) (+)·NO(3) (−), all atoms except the methyl H atoms lie on a crystallographic mirror plane. The interlayer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å. Two-dimensional C—H⋯O hydrogen-bonded networks link cations to anions, while C—H⋯N interactions link cations within each layer. Anion–π interactions with the cations assist in binding the layers together. |
| format | Online Article Text |
| id | pubmed-3379252 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33792522012-06-20 2-Cyano-1-methylpyridinium nitrate Koplitz, Lynn V. Mague, Joel T. Kammer, Michael N. McCormick, Cameron A. Renfro, Heather E. Vumbaco, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(7)N(2) (+)·NO(3) (−), all atoms except the methyl H atoms lie on a crystallographic mirror plane. The interlayer distance, including that between aligned N atoms from alternating cations and anions in adjacent layers, is exceptionally short at 3.055 (1) Å. Two-dimensional C—H⋯O hydrogen-bonded networks link cations to anions, while C—H⋯N interactions link cations within each layer. Anion–π interactions with the cations assist in binding the layers together. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379252/ /pubmed/22719450 http://dx.doi.org/10.1107/S1600536812019460 Text en © Koplitz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Koplitz, Lynn V. Mague, Joel T. Kammer, Michael N. McCormick, Cameron A. Renfro, Heather E. Vumbaco, David J. 2-Cyano-1-methylpyridinium nitrate |
| title | 2-Cyano-1-methylpyridinium nitrate |
| title_full | 2-Cyano-1-methylpyridinium nitrate |
| title_fullStr | 2-Cyano-1-methylpyridinium nitrate |
| title_full_unstemmed | 2-Cyano-1-methylpyridinium nitrate |
| title_short | 2-Cyano-1-methylpyridinium nitrate |
| title_sort | 2-cyano-1-methylpyridinium nitrate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379252/ https://www.ncbi.nlm.nih.gov/pubmed/22719450 http://dx.doi.org/10.1107/S1600536812019460 |
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