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(E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate
The benzohydrazide molecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, w...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379254/ https://www.ncbi.nlm.nih.gov/pubmed/22719452 http://dx.doi.org/10.1107/S1600536812019356 |
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author | Fun, Hoong-Kun Horkaew, Jirapa Chantrapromma, Suchada Karalai, Chatchanok |
author_facet | Fun, Hoong-Kun Horkaew, Jirapa Chantrapromma, Suchada Karalai, Chatchanok |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The benzohydrazide molecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, with the hydroxy- and ethoxy-substituted benzene rings. The dihedral angle between these benzene rings is 3.82 (7)°. The ethoxy group is almost coplanar with the attached benzene ring with a C—O—C—C torsion angle of −176.58 (11)°. In the crystal, the benzohydrazide and water molecules are linked by N—H⋯O, O—H⋯O , O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3379254 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33792542012-06-20 (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate Fun, Hoong-Kun Horkaew, Jirapa Chantrapromma, Suchada Karalai, Chatchanok Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzohydrazide molecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, with the hydroxy- and ethoxy-substituted benzene rings. The dihedral angle between these benzene rings is 3.82 (7)°. The ethoxy group is almost coplanar with the attached benzene ring with a C—O—C—C torsion angle of −176.58 (11)°. In the crystal, the benzohydrazide and water molecules are linked by N—H⋯O, O—H⋯O , O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379254/ /pubmed/22719452 http://dx.doi.org/10.1107/S1600536812019356 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Horkaew, Jirapa Chantrapromma, Suchada Karalai, Chatchanok (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
title | (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
title_full | (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
title_fullStr | (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
title_full_unstemmed | (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
title_short | (E)-N′-(4-Ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
title_sort | (e)-n′-(4-ethoxybenzylidene)-4-hydroxybenzohydrazide dihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379254/ https://www.ncbi.nlm.nih.gov/pubmed/22719452 http://dx.doi.org/10.1107/S1600536812019356 |
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