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(E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate

The benzohydrazide mol­ecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, w...

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Autores principales: Fun, Hoong-Kun, Horkaew, Jirapa, Chantrapromma, Suchada, Karalai, Chatchanok
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379254/
https://www.ncbi.nlm.nih.gov/pubmed/22719452
http://dx.doi.org/10.1107/S1600536812019356
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author Fun, Hoong-Kun
Horkaew, Jirapa
Chantrapromma, Suchada
Karalai, Chatchanok
author_facet Fun, Hoong-Kun
Horkaew, Jirapa
Chantrapromma, Suchada
Karalai, Chatchanok
author_sort Fun, Hoong-Kun
collection PubMed
description The benzohydrazide mol­ecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, with the hy­droxy- and eth­oxy-substituted benzene rings. The dihedral angle between these benzene rings is 3.82 (7)°. The eth­oxy group is almost coplanar with the attached benzene ring with a C—O—C—C torsion angle of −176.58 (11)°. In the crystal, the benzohydrazide and water mol­ecules are linked by N—H⋯O, O—H⋯O , O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-33792542012-06-20 (E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate Fun, Hoong-Kun Horkaew, Jirapa Chantrapromma, Suchada Karalai, Chatchanok Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzohydrazide mol­ecule of the title compound, C(16)H(16)N(2)O(3)·2H(2)O, exists in a trans conformation with respect to the C=N double bond. The central O=C—NH—N=C plane [r.m.s. deviation of 0.0165 (1) Å for the five non-H atoms] makes dihedral angles of 6.04 (8) and 2.38 (8)°, respectively, with the hy­droxy- and eth­oxy-substituted benzene rings. The dihedral angle between these benzene rings is 3.82 (7)°. The eth­oxy group is almost coplanar with the attached benzene ring with a C—O—C—C torsion angle of −176.58 (11)°. In the crystal, the benzohydrazide and water mol­ecules are linked by N—H⋯O, O—H⋯O , O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2012-05-05 /pmc/articles/PMC3379254/ /pubmed/22719452 http://dx.doi.org/10.1107/S1600536812019356 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Horkaew, Jirapa
Chantrapromma, Suchada
Karalai, Chatchanok
(E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
title (E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
title_full (E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
title_fullStr (E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
title_full_unstemmed (E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
title_short (E)-N′-(4-Eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
title_sort (e)-n′-(4-eth­oxy­benzyl­idene)-4-hy­droxy­benzohydrazide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379254/
https://www.ncbi.nlm.nih.gov/pubmed/22719452
http://dx.doi.org/10.1107/S1600536812019356
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