3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde

In the title compound, C(21)H(21)N(3)O(2), the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine...

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Detalles Bibliográficos
Autores principales: Wang, Ruo-Xu, Gao, Da-Zhi, Ye, Fan, Wu, Yan-Fei, Zhu, Dun-Ru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379269/
https://www.ncbi.nlm.nih.gov/pubmed/22719467
http://dx.doi.org/10.1107/S1600536812019940
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author Wang, Ruo-Xu
Gao, Da-Zhi
Ye, Fan
Wu, Yan-Fei
Zhu, Dun-Ru
author_facet Wang, Ruo-Xu
Gao, Da-Zhi
Ye, Fan
Wu, Yan-Fei
Zhu, Dun-Ru
author_sort Wang, Ruo-Xu
collection PubMed
description In the title compound, C(21)H(21)N(3)O(2), the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The mol­ecular conformation is stabilized by intramolecular bifurcated O—H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C—H⋯N hydrogen bonds.
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spelling pubmed-33792692012-06-20 3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde Wang, Ruo-Xu Gao, Da-Zhi Ye, Fan Wu, Yan-Fei Zhu, Dun-Ru Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(21)N(3)O(2), the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The mol­ecular conformation is stabilized by intramolecular bifurcated O—H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C—H⋯N hydrogen bonds. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379269/ /pubmed/22719467 http://dx.doi.org/10.1107/S1600536812019940 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Ruo-Xu
Gao, Da-Zhi
Ye, Fan
Wu, Yan-Fei
Zhu, Dun-Ru
3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
title 3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
title_full 3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
title_fullStr 3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
title_full_unstemmed 3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
title_short 3-{[Bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
title_sort 3-{[bis(pyridin-2-ylmeth­yl)amino]­meth­yl}-2-hy­droxy-5-methyl­benz­aldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379269/
https://www.ncbi.nlm.nih.gov/pubmed/22719467
http://dx.doi.org/10.1107/S1600536812019940
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