4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione

The asymmetric unit of the title compound, C(12)H(13)BrN(4)OS, contains two independent mol­ecules in which the dihedral angles between the triazole and benzene rings are 2.9 (3) and 7.5 (3)°. The thione group is of the form R (2)C=S. An intra­molecular O—H⋯N hydrogen bond occurs in each mol­ecule....

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Detalles Bibliográficos
Autores principales: Wu, Xin, Yuan, Cai-Xia, Ma, Ling, Zhai, Kai-Lu, Zhu, Miao-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379270/
https://www.ncbi.nlm.nih.gov/pubmed/22719468
http://dx.doi.org/10.1107/S1600536812019745
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author Wu, Xin
Yuan, Cai-Xia
Ma, Ling
Zhai, Kai-Lu
Zhu, Miao-Li
author_facet Wu, Xin
Yuan, Cai-Xia
Ma, Ling
Zhai, Kai-Lu
Zhu, Miao-Li
author_sort Wu, Xin
collection PubMed
description The asymmetric unit of the title compound, C(12)H(13)BrN(4)OS, contains two independent mol­ecules in which the dihedral angles between the triazole and benzene rings are 2.9 (3) and 7.5 (3)°. The thione group is of the form R (2)C=S. An intra­molecular O—H⋯N hydrogen bond occurs in each mol­ecule. The crystal structure features weak N—H⋯S inter­actions and π–π stacking of the benzene rings [centroid–centroid distance = 3.667 (3) Å].
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spelling pubmed-33792702012-06-20 4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione Wu, Xin Yuan, Cai-Xia Ma, Ling Zhai, Kai-Lu Zhu, Miao-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(12)H(13)BrN(4)OS, contains two independent mol­ecules in which the dihedral angles between the triazole and benzene rings are 2.9 (3) and 7.5 (3)°. The thione group is of the form R (2)C=S. An intra­molecular O—H⋯N hydrogen bond occurs in each mol­ecule. The crystal structure features weak N—H⋯S inter­actions and π–π stacking of the benzene rings [centroid–centroid distance = 3.667 (3) Å]. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379270/ /pubmed/22719468 http://dx.doi.org/10.1107/S1600536812019745 Text en © Wu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, Xin
Yuan, Cai-Xia
Ma, Ling
Zhai, Kai-Lu
Zhu, Miao-Li
4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione
title 4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione
title_full 4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione
title_fullStr 4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione
title_full_unstemmed 4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione
title_short 4-[(5-Bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1H-1,2,4-triazole-5(4H)-thione
title_sort 4-[(5-bromo-2-hy­droxy­benzyl­idene)amino]-3-propyl-1h-1,2,4-triazole-5(4h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379270/
https://www.ncbi.nlm.nih.gov/pubmed/22719468
http://dx.doi.org/10.1107/S1600536812019745
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