2-(Pyridin-2-yl)-1,3-oxathiane

The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C—C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic com...

Descripción completa

Detalles Bibliográficos
Autores principales: Turner, David, Fratini, Albert, Turro, Claudia, Check, Michael, Hunter, Chad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379271/
https://www.ncbi.nlm.nih.gov/pubmed/22719469
http://dx.doi.org/10.1107/S1600536812018661
_version_ 1782236161620574208
author Turner, David
Fratini, Albert
Turro, Claudia
Check, Michael
Hunter, Chad
author_facet Turner, David
Fratini, Albert
Turro, Claudia
Check, Michael
Hunter, Chad
author_sort Turner, David
collection PubMed
description The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C—C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes. The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring. The corresponding S—C—C—N torsion angle is 69.07 (14)°. In the crystal, mol­ecules aggregate as centrosymmetric pairs connected by pairs of C—H⋯N hydrogen bonds.
format Online
Article
Text
id pubmed-3379271
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33792712012-06-20 2-(Pyridin-2-yl)-1,3-oxathiane Turner, David Fratini, Albert Turro, Claudia Check, Michael Hunter, Chad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(11)NOS, exhibits a unique structural motif, with free rotation of the aliphatic oxathiane ring about the C—C bond connecting this moiety to the aromatic pyridine ring. The structure elucidation was undertaken due to its potential as a bidentate ligand for organometallic complexes. The oxathiane ring adopts the expected chair conformation, with the S atom in proximity to the N atom on the pyridine ring. The corresponding S—C—C—N torsion angle is 69.07 (14)°. In the crystal, mol­ecules aggregate as centrosymmetric pairs connected by pairs of C—H⋯N hydrogen bonds. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379271/ /pubmed/22719469 http://dx.doi.org/10.1107/S1600536812018661 Text en © Turner et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Turner, David
Fratini, Albert
Turro, Claudia
Check, Michael
Hunter, Chad
2-(Pyridin-2-yl)-1,3-oxathiane
title 2-(Pyridin-2-yl)-1,3-oxathiane
title_full 2-(Pyridin-2-yl)-1,3-oxathiane
title_fullStr 2-(Pyridin-2-yl)-1,3-oxathiane
title_full_unstemmed 2-(Pyridin-2-yl)-1,3-oxathiane
title_short 2-(Pyridin-2-yl)-1,3-oxathiane
title_sort 2-(pyridin-2-yl)-1,3-oxathiane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379271/
https://www.ncbi.nlm.nih.gov/pubmed/22719469
http://dx.doi.org/10.1107/S1600536812018661
work_keys_str_mv AT turnerdavid 2pyridin2yl13oxathiane
AT fratinialbert 2pyridin2yl13oxathiane
AT turroclaudia 2pyridin2yl13oxathiane
AT checkmichael 2pyridin2yl13oxathiane
AT hunterchad 2pyridin2yl13oxathiane

Ejemplares similares