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2-Phenyl-N′-(2-phenylacetyl)acetohydrazide
In the title compound, C(16)H(16)N(2)O(2), the N′-acetylacetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379276/ https://www.ncbi.nlm.nih.gov/pubmed/22719474 http://dx.doi.org/10.1107/S1600536812019861 |
Sumario: | In the title compound, C(16)H(16)N(2)O(2), the N′-acetylacetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In the crystal, molecules are linked into sheets lying parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. One O atom accepts one N—H⋯O and one C—H⋯O hydrogen bond and the other O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds. The N—H⋯O hydrogen bonds lead to R (2) (2)(8) loops and the C—H⋯O hydrogen bonds generate R (2) (1)(6) loops. |
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