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2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide

In the title compound, C(16)H(16)N(2)O(2), the N′-acetyl­acetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In...

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Detalles Bibliográficos
Autores principales: Abdel-Aziz, Hatem A., Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379276/
https://www.ncbi.nlm.nih.gov/pubmed/22719474
http://dx.doi.org/10.1107/S1600536812019861
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author Abdel-Aziz, Hatem A.
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Abdel-Aziz, Hatem A.
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Abdel-Aziz, Hatem A.
collection PubMed
description In the title compound, C(16)H(16)N(2)O(2), the N′-acetyl­acetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In the crystal, mol­ecules are linked into sheets lying parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. One O atom accepts one N—H⋯O and one C—H⋯O hydrogen bond and the other O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds. The N—H⋯O hydrogen bonds lead to R (2) (2)(8) loops and the C—H⋯O hydrogen bonds generate R (2) (1)(6) loops.
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spelling pubmed-33792762012-06-20 2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide Abdel-Aziz, Hatem A. Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(2)O(2), the N′-acetyl­acetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In the crystal, mol­ecules are linked into sheets lying parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. One O atom accepts one N—H⋯O and one C—H⋯O hydrogen bond and the other O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds. The N—H⋯O hydrogen bonds lead to R (2) (2)(8) loops and the C—H⋯O hydrogen bonds generate R (2) (1)(6) loops. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379276/ /pubmed/22719474 http://dx.doi.org/10.1107/S1600536812019861 Text en © Abdel-Aziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Aziz, Hatem A.
Quah, Ching Kheng
Fun, Hoong-Kun
2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide
title 2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide
title_full 2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide
title_fullStr 2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide
title_full_unstemmed 2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide
title_short 2-Phenyl-N′-(2-phenyl­acet­yl)acetohydrazide
title_sort 2-phenyl-n′-(2-phenyl­acet­yl)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379276/
https://www.ncbi.nlm.nih.gov/pubmed/22719474
http://dx.doi.org/10.1107/S1600536812019861
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