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2-Phenyl-N′-(2-phenylacetyl)acetohydrazide
In the title compound, C(16)H(16)N(2)O(2), the N′-acetylacetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379276/ https://www.ncbi.nlm.nih.gov/pubmed/22719474 http://dx.doi.org/10.1107/S1600536812019861 |
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author | Abdel-Aziz, Hatem A. Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Abdel-Aziz, Hatem A. Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Abdel-Aziz, Hatem A. |
collection | PubMed |
description | In the title compound, C(16)H(16)N(2)O(2), the N′-acetylacetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In the crystal, molecules are linked into sheets lying parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. One O atom accepts one N—H⋯O and one C—H⋯O hydrogen bond and the other O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds. The N—H⋯O hydrogen bonds lead to R (2) (2)(8) loops and the C—H⋯O hydrogen bonds generate R (2) (1)(6) loops. |
format | Online Article Text |
id | pubmed-3379276 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33792762012-06-20 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide Abdel-Aziz, Hatem A. Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(2)O(2), the N′-acetylacetohydrazide group is approximately planar (r.m.s. deviation = 0.018 Å for the eight non-H atoms) and makes dihedral angles of 81.92 (6) and 65.19 (6)° with the terminal phenyl rings. The phenyl rings form a dihedral angle of 62.60 (7)°. In the crystal, molecules are linked into sheets lying parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. One O atom accepts one N—H⋯O and one C—H⋯O hydrogen bond and the other O atom accepts one N—H⋯O and two C—H⋯O hydrogen bonds. The N—H⋯O hydrogen bonds lead to R (2) (2)(8) loops and the C—H⋯O hydrogen bonds generate R (2) (1)(6) loops. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379276/ /pubmed/22719474 http://dx.doi.org/10.1107/S1600536812019861 Text en © Abdel-Aziz et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Abdel-Aziz, Hatem A. Quah, Ching Kheng Fun, Hoong-Kun 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide |
title | 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide |
title_full | 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide |
title_fullStr | 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide |
title_full_unstemmed | 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide |
title_short | 2-Phenyl-N′-(2-phenylacetyl)acetohydrazide |
title_sort | 2-phenyl-n′-(2-phenylacetyl)acetohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379276/ https://www.ncbi.nlm.nih.gov/pubmed/22719474 http://dx.doi.org/10.1107/S1600536812019861 |
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