Decachloro­hexa-1,5-diene

The title compound, C(6)Cl(10), cystallizes in a nearly C2-symmetrical gauche conformation. Both trichloro­vinyl groups are nearly planar [Cl—C—C—Cl torsion angles = −178.47 (12) and −179.93 (11)°] and the lengths of their C—Cl bonds increase from the terminal trans and cis C—Cl bonds to the inter­n...

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Detalles Bibliográficos
Autores principales: Schollmeyer, Dieter, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379281/
https://www.ncbi.nlm.nih.gov/pubmed/22719479
http://dx.doi.org/10.1107/S1600536812019769
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author Schollmeyer, Dieter
Detert, Heiner
author_facet Schollmeyer, Dieter
Detert, Heiner
author_sort Schollmeyer, Dieter
collection PubMed
description The title compound, C(6)Cl(10), cystallizes in a nearly C2-symmetrical gauche conformation. Both trichloro­vinyl groups are nearly planar [Cl—C—C—Cl torsion angles = −178.47 (12) and −179.93 (11)°] and the lengths of their C—Cl bonds increase from the terminal trans and cis C—Cl bonds to the inter­nal bonds. The Cl—C—Cl bond angles of the terminal dichloro­methyl­ene units are compressed to 111.75 (11) and 111.40 (11)°.
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spelling pubmed-33792812012-06-20 Decachloro­hexa-1,5-diene Schollmeyer, Dieter Detert, Heiner Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)Cl(10), cystallizes in a nearly C2-symmetrical gauche conformation. Both trichloro­vinyl groups are nearly planar [Cl—C—C—Cl torsion angles = −178.47 (12) and −179.93 (11)°] and the lengths of their C—Cl bonds increase from the terminal trans and cis C—Cl bonds to the inter­nal bonds. The Cl—C—Cl bond angles of the terminal dichloro­methyl­ene units are compressed to 111.75 (11) and 111.40 (11)°. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379281/ /pubmed/22719479 http://dx.doi.org/10.1107/S1600536812019769 Text en © Schollmeyer and Detert 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schollmeyer, Dieter
Detert, Heiner
Decachloro­hexa-1,5-diene
title Decachloro­hexa-1,5-diene
title_full Decachloro­hexa-1,5-diene
title_fullStr Decachloro­hexa-1,5-diene
title_full_unstemmed Decachloro­hexa-1,5-diene
title_short Decachloro­hexa-1,5-diene
title_sort decachloro­hexa-1,5-diene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379281/
https://www.ncbi.nlm.nih.gov/pubmed/22719479
http://dx.doi.org/10.1107/S1600536812019769
work_keys_str_mv AT schollmeyerdieter decachlorohexa15diene
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