4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride

In the title compound, C(9)H(13)N(2)O(+)·Cl(−), the cation, apart from the methyl groups, is almost planar, with a maximum deviation of 0.040 (1) Å; the methyl C atoms deviate by 0.389 (2) and −1.247 (1) Å, from the mean plane. In the crystal, cations and anions associate through C—H⋯Cl hydrogen bon...

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Autores principales: Devi, T. Uma, Kalpana, G., Priya, S., Ravikumar, K., Selvanayagam, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379298/
https://www.ncbi.nlm.nih.gov/pubmed/22719496
http://dx.doi.org/10.1107/S1600536812020211
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author Devi, T. Uma
Kalpana, G.
Priya, S.
Ravikumar, K.
Selvanayagam, S.
author_facet Devi, T. Uma
Kalpana, G.
Priya, S.
Ravikumar, K.
Selvanayagam, S.
author_sort Devi, T. Uma
collection PubMed
description In the title compound, C(9)H(13)N(2)O(+)·Cl(−), the cation, apart from the methyl groups, is almost planar, with a maximum deviation of 0.040 (1) Å; the methyl C atoms deviate by 0.389 (2) and −1.247 (1) Å, from the mean plane. In the crystal, cations and anions associate through C—H⋯Cl hydrogen bonds, forming a helical arrangement. In addition, inter­molecular O—H⋯Cl, N—H⋯Cl and C—H⋯N inter­actions are observed.
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spelling pubmed-33792982012-06-20 4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride Devi, T. Uma Kalpana, G. Priya, S. Ravikumar, K. Selvanayagam, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(13)N(2)O(+)·Cl(−), the cation, apart from the methyl groups, is almost planar, with a maximum deviation of 0.040 (1) Å; the methyl C atoms deviate by 0.389 (2) and −1.247 (1) Å, from the mean plane. In the crystal, cations and anions associate through C—H⋯Cl hydrogen bonds, forming a helical arrangement. In addition, inter­molecular O—H⋯Cl, N—H⋯Cl and C—H⋯N inter­actions are observed. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379298/ /pubmed/22719496 http://dx.doi.org/10.1107/S1600536812020211 Text en © Devi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Devi, T. Uma
Kalpana, G.
Priya, S.
Ravikumar, K.
Selvanayagam, S.
4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride
title 4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride
title_full 4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride
title_fullStr 4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride
title_full_unstemmed 4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride
title_short 4-[(E)-(Hy­droxy­imino)­meth­yl]-N,N-di­methyl­anilinium chloride
title_sort 4-[(e)-(hy­droxy­imino)­meth­yl]-n,n-di­methyl­anilinium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379298/
https://www.ncbi.nlm.nih.gov/pubmed/22719496
http://dx.doi.org/10.1107/S1600536812020211
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AT ravikumark 4ehydroxyiminomethylnndimethylaniliniumchloride
AT selvanayagams 4ehydroxyiminomethylnndimethylaniliniumchloride

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