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4,4′-Bipyridine–terephthalic acid (1/1)
The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-molecule of each moiety, 4,4′-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong intermolecular O—H⋯N hydrogen bonds,...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379304/ https://www.ncbi.nlm.nih.gov/pubmed/22719502 http://dx.doi.org/10.1107/S1600536812021113 |
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author | Koteswara Rao, Vandavasi Zeller, Matthias Lovelace-Cameron, Sherri R. |
author_facet | Koteswara Rao, Vandavasi Zeller, Matthias Lovelace-Cameron, Sherri R. |
author_sort | Koteswara Rao, Vandavasi |
collection | PubMed |
description | The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-molecule of each moiety, 4,4′-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong intermolecular O—H⋯N hydrogen bonds, forming infinite chains propagating along [1-21]. The chains are further connected through C—H⋯O interactions giving sheets in (012). The sheets are linked via π–π interactions between the bpy rings and the bdc–bpy rings [centroid–centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supramolecular layer-like structure. |
format | Online Article Text |
id | pubmed-3379304 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33793042012-06-20 4,4′-Bipyridine–terephthalic acid (1/1) Koteswara Rao, Vandavasi Zeller, Matthias Lovelace-Cameron, Sherri R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-molecule of each moiety, 4,4′-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong intermolecular O—H⋯N hydrogen bonds, forming infinite chains propagating along [1-21]. The chains are further connected through C—H⋯O interactions giving sheets in (012). The sheets are linked via π–π interactions between the bpy rings and the bdc–bpy rings [centroid–centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supramolecular layer-like structure. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379304/ /pubmed/22719502 http://dx.doi.org/10.1107/S1600536812021113 Text en © Koteswara Rao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Koteswara Rao, Vandavasi Zeller, Matthias Lovelace-Cameron, Sherri R. 4,4′-Bipyridine–terephthalic acid (1/1) |
title | 4,4′-Bipyridine–terephthalic acid (1/1) |
title_full | 4,4′-Bipyridine–terephthalic acid (1/1) |
title_fullStr | 4,4′-Bipyridine–terephthalic acid (1/1) |
title_full_unstemmed | 4,4′-Bipyridine–terephthalic acid (1/1) |
title_short | 4,4′-Bipyridine–terephthalic acid (1/1) |
title_sort | 4,4′-bipyridine–terephthalic acid (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379304/ https://www.ncbi.nlm.nih.gov/pubmed/22719502 http://dx.doi.org/10.1107/S1600536812021113 |
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