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4,4′-Bipyridine–terephthalic acid (1/1)

The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol­ecule of each moiety, 4,4′-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong inter­molecular O—H⋯N hydrogen bonds,...

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Detalles Bibliográficos
Autores principales: Koteswara Rao, Vandavasi, Zeller, Matthias, Lovelace-Cameron, Sherri R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379304/
https://www.ncbi.nlm.nih.gov/pubmed/22719502
http://dx.doi.org/10.1107/S1600536812021113
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author Koteswara Rao, Vandavasi
Zeller, Matthias
Lovelace-Cameron, Sherri R.
author_facet Koteswara Rao, Vandavasi
Zeller, Matthias
Lovelace-Cameron, Sherri R.
author_sort Koteswara Rao, Vandavasi
collection PubMed
description The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol­ecule of each moiety, 4,4′-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong inter­molecular O—H⋯N hydrogen bonds, forming infinite chains propagating along [1-21]. The chains are further connected through C—H⋯O inter­actions giving sheets in (012). The sheets are linked via π–π inter­actions between the bpy rings and the bdc–bpy rings [centroid–centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supra­molecular layer-like structure.
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spelling pubmed-33793042012-06-20 4,4′-Bipyridine–terephthalic acid (1/1) Koteswara Rao, Vandavasi Zeller, Matthias Lovelace-Cameron, Sherri R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(8)N(2)·C(8)H(6)O(4), consists of one half-mol­ecule of each moiety, 4,4′-bipyridine (bpy) and terephthalic acid (bdc), both being located on crystallographic inversion centers. They are linked together via strong inter­molecular O—H⋯N hydrogen bonds, forming infinite chains propagating along [1-21]. The chains are further connected through C—H⋯O inter­actions giving sheets in (012). The sheets are linked via π–π inter­actions between the bpy rings and the bdc–bpy rings [centroid–centroid distances = 3.690 (2) and 3.869 (2) Å], resulting in the formation of a three-dimensional supra­molecular layer-like structure. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379304/ /pubmed/22719502 http://dx.doi.org/10.1107/S1600536812021113 Text en © Koteswara Rao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Koteswara Rao, Vandavasi
Zeller, Matthias
Lovelace-Cameron, Sherri R.
4,4′-Bipyridine–terephthalic acid (1/1)
title 4,4′-Bipyridine–terephthalic acid (1/1)
title_full 4,4′-Bipyridine–terephthalic acid (1/1)
title_fullStr 4,4′-Bipyridine–terephthalic acid (1/1)
title_full_unstemmed 4,4′-Bipyridine–terephthalic acid (1/1)
title_short 4,4′-Bipyridine–terephthalic acid (1/1)
title_sort 4,4′-bipyridine–terephthalic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379304/
https://www.ncbi.nlm.nih.gov/pubmed/22719502
http://dx.doi.org/10.1107/S1600536812021113
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