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(E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one
In the title compound, C(11)H(15)NOS, the 3-(dimethylamino)prop-2-en-1-one unit is approximately planar [maximum deviation = 0.0975 (14) Å] and its mean plane of seven non-H atoms makes a dihedral angle of 6.96 (10)° with the thiophene ring. In the crystal, molecules are linked by pairs of C—H⋯O...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379305/ https://www.ncbi.nlm.nih.gov/pubmed/22719503 http://dx.doi.org/10.1107/S1600536812021022 |
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author | Ghorab, Mostafa M. Al-Said, Mansour S. Ghabbour, Hazem A. Chia, Tze Shyang Fun, Hoong-Kun |
author_facet | Ghorab, Mostafa M. Al-Said, Mansour S. Ghabbour, Hazem A. Chia, Tze Shyang Fun, Hoong-Kun |
author_sort | Ghorab, Mostafa M. |
collection | PubMed |
description | In the title compound, C(11)H(15)NOS, the 3-(dimethylamino)prop-2-en-1-one unit is approximately planar [maximum deviation = 0.0975 (14) Å] and its mean plane of seven non-H atoms makes a dihedral angle of 6.96 (10)° with the thiophene ring. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers with R (2) (2)(14) ring motifs. The dimers are stacked along the c axis through C—H⋯π interactions. The two methyl groups, attached to the thiophene ring and the amino N atom, are each disordered over two orientations, with site-occupancy ratios of 0.59 (4):0.41 (4) and 0.74 (4):0.26 (4), respectively. |
format | Online Article Text |
id | pubmed-3379305 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33793052012-06-20 (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one Ghorab, Mostafa M. Al-Said, Mansour S. Ghabbour, Hazem A. Chia, Tze Shyang Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(15)NOS, the 3-(dimethylamino)prop-2-en-1-one unit is approximately planar [maximum deviation = 0.0975 (14) Å] and its mean plane of seven non-H atoms makes a dihedral angle of 6.96 (10)° with the thiophene ring. In the crystal, molecules are linked by pairs of C—H⋯O hydrogen bonds into inversion dimers with R (2) (2)(14) ring motifs. The dimers are stacked along the c axis through C—H⋯π interactions. The two methyl groups, attached to the thiophene ring and the amino N atom, are each disordered over two orientations, with site-occupancy ratios of 0.59 (4):0.41 (4) and 0.74 (4):0.26 (4), respectively. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379305/ /pubmed/22719503 http://dx.doi.org/10.1107/S1600536812021022 Text en © Ghorab et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ghorab, Mostafa M. Al-Said, Mansour S. Ghabbour, Hazem A. Chia, Tze Shyang Fun, Hoong-Kun (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
title | (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
title_full | (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
title_fullStr | (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
title_full_unstemmed | (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
title_short | (E)-3-Dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
title_sort | (e)-3-dimethylamino-1-(2,5-dimethylthiophen-3-yl)prop-2-en-1-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379305/ https://www.ncbi.nlm.nih.gov/pubmed/22719503 http://dx.doi.org/10.1107/S1600536812021022 |
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