1,4-Ditosyl-1,4-diazepane

In the title compound, C(19)H(24)N(2)O(4)S(2), the dihedral angle formed by the benzene rings is 82.88 (7)°, and the mol­ecular conformation is enforced by weak intra­molecular C—H⋯O contacts. Two C atoms of the 1,4-diazepane ring are disordered over two sets of sites with a refined occupancy ratio...

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Detalles Bibliográficos
Autores principales: Yang, Shuang-Hua, Zhai, Zhi-Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379307/
https://www.ncbi.nlm.nih.gov/pubmed/22719505
http://dx.doi.org/10.1107/S1600536812020958
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author Yang, Shuang-Hua
Zhai, Zhi-Wei
author_facet Yang, Shuang-Hua
Zhai, Zhi-Wei
author_sort Yang, Shuang-Hua
collection PubMed
description In the title compound, C(19)H(24)N(2)O(4)S(2), the dihedral angle formed by the benzene rings is 82.88 (7)°, and the mol­ecular conformation is enforced by weak intra­molecular C—H⋯O contacts. Two C atoms of the 1,4-diazepane ring are disordered over two sets of sites with a refined occupancy ratio of 0.534 (13):0.466 (13). In the crystal, mol­ecules are linked by weak inter­molecular C—H⋯O inter­actions into chains parallel to the a axis.
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spelling pubmed-33793072012-06-20 1,4-Ditosyl-1,4-diazepane Yang, Shuang-Hua Zhai, Zhi-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(24)N(2)O(4)S(2), the dihedral angle formed by the benzene rings is 82.88 (7)°, and the mol­ecular conformation is enforced by weak intra­molecular C—H⋯O contacts. Two C atoms of the 1,4-diazepane ring are disordered over two sets of sites with a refined occupancy ratio of 0.534 (13):0.466 (13). In the crystal, mol­ecules are linked by weak inter­molecular C—H⋯O inter­actions into chains parallel to the a axis. International Union of Crystallography 2012-05-12 /pmc/articles/PMC3379307/ /pubmed/22719505 http://dx.doi.org/10.1107/S1600536812020958 Text en © Yang and Zhai 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Shuang-Hua
Zhai, Zhi-Wei
1,4-Ditosyl-1,4-diazepane
title 1,4-Ditosyl-1,4-diazepane
title_full 1,4-Ditosyl-1,4-diazepane
title_fullStr 1,4-Ditosyl-1,4-diazepane
title_full_unstemmed 1,4-Ditosyl-1,4-diazepane
title_short 1,4-Ditosyl-1,4-diazepane
title_sort 1,4-ditosyl-1,4-diazepane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379307/
https://www.ncbi.nlm.nih.gov/pubmed/22719505
http://dx.doi.org/10.1107/S1600536812020958
work_keys_str_mv AT yangshuanghua 14ditosyl14diazepane
AT zhaizhiwei 14ditosyl14diazepane

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