2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione

The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all lo...

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Detalles Bibliográficos
Autores principales: Ioannou, Savvas, Moushi, Eleni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379310/
https://www.ncbi.nlm.nih.gov/pubmed/22719508
http://dx.doi.org/10.1107/S160053681202079X
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author Ioannou, Savvas
Moushi, Eleni
author_facet Ioannou, Savvas
Moushi, Eleni
author_sort Ioannou, Savvas
collection PubMed
description The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C—O bonds. The C—C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C—C bonds of the mol­ecule due to the stretch of the cage structure.
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spelling pubmed-33793102012-06-20 2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione Ioannou, Savvas Moushi, Eleni Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(9)H(12)O(4)S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C—O bonds. The C—C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C—C bonds of the mol­ecule due to the stretch of the cage structure. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379310/ /pubmed/22719508 http://dx.doi.org/10.1107/S160053681202079X Text en © Ioannou and Moushi 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ioannou, Savvas
Moushi, Eleni
2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
title 2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
title_full 2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
title_fullStr 2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
title_full_unstemmed 2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
title_short 2,4-Dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
title_sort 2,4-dioxa-λ(6)-thia­tetra­cyclo­[5.3.1.1(5,9).0(1,5)]dodecane-3,3-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379310/
https://www.ncbi.nlm.nih.gov/pubmed/22719508
http://dx.doi.org/10.1107/S160053681202079X
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