9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), adjacent cations are linked through C—Br⋯π and π–π contacts [centroid–centroid distance = 3.744 (2) Å], and neighbouring cations and anions via C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring sy...

Descripción completa

Detalles Bibliográficos
Autores principales: Trzybiński, Damian, Sieradzan, Andrzej, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379313/
https://www.ncbi.nlm.nih.gov/pubmed/22719511
http://dx.doi.org/10.1107/S1600536812020892
_version_ 1782236171249647616
author Trzybiński, Damian
Sieradzan, Andrzej
Krzymiński, Karol
Błażejowski, Jerzy
author_facet Trzybiński, Damian
Sieradzan, Andrzej
Krzymiński, Karol
Błażejowski, Jerzy
author_sort Trzybiński, Damian
collection PubMed
description In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), adjacent cations are linked through C—Br⋯π and π–π contacts [centroid–centroid distance = 3.744 (2) Å], and neighbouring cations and anions via C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°. The carb­oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8 (1)° in the lattice.
format Online
Article
Text
id pubmed-3379313
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33793132012-06-20 9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate Trzybiński, Damian Sieradzan, Andrzej Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), adjacent cations are linked through C—Br⋯π and π–π contacts [centroid–centroid distance = 3.744 (2) Å], and neighbouring cations and anions via C—H⋯O, C—F⋯π and S—O⋯π inter­actions. The acridine and benzene ring systems are oriented at a dihedral angle of 18.7 (1)°. The carb­oxy group is twisted at an angle of 69.3 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine moieties are either parallel or inclined at an angle of 27.8 (1)° in the lattice. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379313/ /pubmed/22719511 http://dx.doi.org/10.1107/S1600536812020892 Text en © Trzybiński et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Trzybiński, Damian
Sieradzan, Andrzej
Krzymiński, Karol
Błażejowski, Jerzy
9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title 9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full 9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_fullStr 9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_short 9-(2-Bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
title_sort 9-(2-bromo­phen­oxy­carbon­yl)-10-methyl­acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379313/
https://www.ncbi.nlm.nih.gov/pubmed/22719511
http://dx.doi.org/10.1107/S1600536812020892
work_keys_str_mv AT trzybinskidamian 92bromophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT sieradzanandrzej 92bromophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT krzyminskikarol 92bromophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 92bromophenoxycarbonyl10methylacridiniumtrifluoromethanesulfonate

Ejemplares similares