2-Amino­cyclo­hexan-1-aminium thio­cyanate

The title compound, C(6)H(15)N(2) (+)·NCS(−), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio­cyanate and cyclo­hexane-1,2-diamine. The cyclo­hexane ring adopts a chair conformation. In the crystal, N—H⋯S and N—H⋯N inter­actions involving the thio­cyanate anion...

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Detalles Bibliográficos
Autores principales: Salem, Halima F., Hasbullah, Siti Aishah, Yamin, Bohari M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379321/
https://www.ncbi.nlm.nih.gov/pubmed/22719519
http://dx.doi.org/10.1107/S1600536812020879
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author Salem, Halima F.
Hasbullah, Siti Aishah
Yamin, Bohari M.
author_facet Salem, Halima F.
Hasbullah, Siti Aishah
Yamin, Bohari M.
author_sort Salem, Halima F.
collection PubMed
description The title compound, C(6)H(15)N(2) (+)·NCS(−), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio­cyanate and cyclo­hexane-1,2-diamine. The cyclo­hexane ring adopts a chair conformation. In the crystal, N—H⋯S and N—H⋯N inter­actions involving the thio­cyanate anion and both the amine and the aminium N atoms link the mol­ecules, forming two-dimensional networks parallel to (001).
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spelling pubmed-33793212012-06-20 2-Amino­cyclo­hexan-1-aminium thio­cyanate Salem, Halima F. Hasbullah, Siti Aishah Yamin, Bohari M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(15)N(2) (+)·NCS(−), was obtained unexpectedly from the reaction mixture of benzoyl chloride, ammonium thio­cyanate and cyclo­hexane-1,2-diamine. The cyclo­hexane ring adopts a chair conformation. In the crystal, N—H⋯S and N—H⋯N inter­actions involving the thio­cyanate anion and both the amine and the aminium N atoms link the mol­ecules, forming two-dimensional networks parallel to (001). International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379321/ /pubmed/22719519 http://dx.doi.org/10.1107/S1600536812020879 Text en © Salem et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Salem, Halima F.
Hasbullah, Siti Aishah
Yamin, Bohari M.
2-Amino­cyclo­hexan-1-aminium thio­cyanate
title 2-Amino­cyclo­hexan-1-aminium thio­cyanate
title_full 2-Amino­cyclo­hexan-1-aminium thio­cyanate
title_fullStr 2-Amino­cyclo­hexan-1-aminium thio­cyanate
title_full_unstemmed 2-Amino­cyclo­hexan-1-aminium thio­cyanate
title_short 2-Amino­cyclo­hexan-1-aminium thio­cyanate
title_sort 2-amino­cyclo­hexan-1-aminium thio­cyanate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379321/
https://www.ncbi.nlm.nih.gov/pubmed/22719519
http://dx.doi.org/10.1107/S1600536812020879
work_keys_str_mv AT salemhalimaf 2aminocyclohexan1aminiumthiocyanate
AT hasbullahsitiaishah 2aminocyclohexan1aminiumthiocyanate
AT yaminboharim 2aminocyclohexan1aminiumthiocyanate

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