(E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide

In the title compound, C(13)H(13)N(3)O, the tetra­hydro­benzene ring adopts a half-boat (envelope) conformation. The mean plane of the tetra­hydro­naphthalene ring system forms a dihedral angle of 9.56 (6)° with the mean plane of the cyano­acetohydrazide group. In the crystal, inversion dimers linke...

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Autores principales: Al-Omar, Mohamed A., Khalifa, Nagy M., Ghabbour, Hazem A., Chia, Tze Shyang, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379327/
https://www.ncbi.nlm.nih.gov/pubmed/22719525
http://dx.doi.org/10.1107/S160053681202106X
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author Al-Omar, Mohamed A.
Khalifa, Nagy M.
Ghabbour, Hazem A.
Chia, Tze Shyang
Fun, Hoong-Kun
author_facet Al-Omar, Mohamed A.
Khalifa, Nagy M.
Ghabbour, Hazem A.
Chia, Tze Shyang
Fun, Hoong-Kun
author_sort Al-Omar, Mohamed A.
collection PubMed
description In the title compound, C(13)H(13)N(3)O, the tetra­hydro­benzene ring adopts a half-boat (envelope) conformation. The mean plane of the tetra­hydro­naphthalene ring system forms a dihedral angle of 9.56 (6)° with the mean plane of the cyano­acetohydrazide group. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are connected by C—H⋯N hydrogen bonds into a chain propagating along [101]. The crystal packing also features C—H⋯π inter­actions.
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spelling pubmed-33793272012-06-20 (E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide Al-Omar, Mohamed A. Khalifa, Nagy M. Ghabbour, Hazem A. Chia, Tze Shyang Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)N(3)O, the tetra­hydro­benzene ring adopts a half-boat (envelope) conformation. The mean plane of the tetra­hydro­naphthalene ring system forms a dihedral angle of 9.56 (6)° with the mean plane of the cyano­acetohydrazide group. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are connected by C—H⋯N hydrogen bonds into a chain propagating along [101]. The crystal packing also features C—H⋯π inter­actions. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379327/ /pubmed/22719525 http://dx.doi.org/10.1107/S160053681202106X Text en © Al-Omar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Al-Omar, Mohamed A.
Khalifa, Nagy M.
Ghabbour, Hazem A.
Chia, Tze Shyang
Fun, Hoong-Kun
(E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
title (E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
title_full (E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
title_fullStr (E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
title_full_unstemmed (E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
title_short (E)-2-Cyano-N′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
title_sort (e)-2-cyano-n′-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379327/
https://www.ncbi.nlm.nih.gov/pubmed/22719525
http://dx.doi.org/10.1107/S160053681202106X
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