3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide

In the title mol­ecule, C(16)H(14)ClF(6)NO, the cyclo­propane ring forms a dihedral angle of 70.82 (18)° with the benzene ring. The torsion angles about the ethyl­ene and amide bonds are −2.2 (5) (Cl—C—C—C) and 0.8 (5)° (O—C—N—C). A supra­molecular chain propagated by glide symmetry along [001] and...

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Detalles Bibliográficos
Autores principales: Rao, Guo-Wu, Li, Xiao-Min, Sun, Na-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379330/
https://www.ncbi.nlm.nih.gov/pubmed/22719528
http://dx.doi.org/10.1107/S1600536812020922
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author Rao, Guo-Wu
Li, Xiao-Min
Sun, Na-Bo
author_facet Rao, Guo-Wu
Li, Xiao-Min
Sun, Na-Bo
author_sort Rao, Guo-Wu
collection PubMed
description In the title mol­ecule, C(16)H(14)ClF(6)NO, the cyclo­propane ring forms a dihedral angle of 70.82 (18)° with the benzene ring. The torsion angles about the ethyl­ene and amide bonds are −2.2 (5) (Cl—C—C—C) and 0.8 (5)° (O—C—N—C). A supra­molecular chain propagated by glide symmetry along [001] and mediated by N—H⋯O hydrogen bonds is observed in the crystal packing.
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spelling pubmed-33793302012-06-20 3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide Rao, Guo-Wu Li, Xiao-Min Sun, Na-Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(16)H(14)ClF(6)NO, the cyclo­propane ring forms a dihedral angle of 70.82 (18)° with the benzene ring. The torsion angles about the ethyl­ene and amide bonds are −2.2 (5) (Cl—C—C—C) and 0.8 (5)° (O—C—N—C). A supra­molecular chain propagated by glide symmetry along [001] and mediated by N—H⋯O hydrogen bonds is observed in the crystal packing. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379330/ /pubmed/22719528 http://dx.doi.org/10.1107/S1600536812020922 Text en © Rao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rao, Guo-Wu
Li, Xiao-Min
Sun, Na-Bo
3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
title 3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
title_full 3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
title_fullStr 3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
title_full_unstemmed 3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
title_short 3-(2-Chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
title_sort 3-(2-chloro-3,3,3-trifluoro­prop-1-en-1-yl)-2,2-dimethyl-n-[3-(trifluoro­meth­yl)phen­yl]cyclo­propane­carboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379330/
https://www.ncbi.nlm.nih.gov/pubmed/22719528
http://dx.doi.org/10.1107/S1600536812020922
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AT sunnabo 32chloro333trifluoroprop1en1yl22dimethyln3trifluoromethylphenylcyclopropanecarboxamide

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