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Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate

The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenyl­acrylate unit. The phenyl ring and methyl acrylate group of the phenyl­acrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0...

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Detalles Bibliográficos
Autores principales: Anuradha, T., Devaraj, A., Seshadri, P. R., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379335/
https://www.ncbi.nlm.nih.gov/pubmed/22719533
http://dx.doi.org/10.1107/S1600536812021009
Descripción
Sumario:The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenyl­acrylate unit. The phenyl ring and methyl acrylate group of the phenyl­acrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0.317 (3), respectively. The mean plane through the benzene ring of the phenyl acrylate makes dihedral angles of 88.4 (8) (major component) and 86.7 (8)° (minor component) with the nitro­phen­oxy ring; the dihedral angle between the two components is 3.64 (6)°. Intra­molecular C—H⋯O interactions stabilise the molecular structure. In the crystal, C—H⋯O inter­actions result in a chain of mol­ecules running along the b axis.