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Methyl (E)-2-[(2-nitrophenoxy)methyl]-3-phenylacrylate
The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenylacrylate unit. The phenyl ring and methyl acrylate group of the phenylacrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379335/ https://www.ncbi.nlm.nih.gov/pubmed/22719533 http://dx.doi.org/10.1107/S1600536812021009 |
Sumario: | The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenylacrylate unit. The phenyl ring and methyl acrylate group of the phenylacrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0.317 (3), respectively. The mean plane through the benzene ring of the phenyl acrylate makes dihedral angles of 88.4 (8) (major component) and 86.7 (8)° (minor component) with the nitrophenoxy ring; the dihedral angle between the two components is 3.64 (6)°. Intramolecular C—H⋯O interactions stabilise the molecular structure. In the crystal, C—H⋯O interactions result in a chain of molecules running along the b axis. |
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