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Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate

The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenyl­acrylate unit. The phenyl ring and methyl acrylate group of the phenyl­acrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0...

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Detalles Bibliográficos
Autores principales: Anuradha, T., Devaraj, A., Seshadri, P. R., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379335/
https://www.ncbi.nlm.nih.gov/pubmed/22719533
http://dx.doi.org/10.1107/S1600536812021009
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author Anuradha, T.
Devaraj, A.
Seshadri, P. R.
Bakthadoss, M.
author_facet Anuradha, T.
Devaraj, A.
Seshadri, P. R.
Bakthadoss, M.
author_sort Anuradha, T.
collection PubMed
description The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenyl­acrylate unit. The phenyl ring and methyl acrylate group of the phenyl­acrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0.317 (3), respectively. The mean plane through the benzene ring of the phenyl acrylate makes dihedral angles of 88.4 (8) (major component) and 86.7 (8)° (minor component) with the nitro­phen­oxy ring; the dihedral angle between the two components is 3.64 (6)°. Intra­molecular C—H⋯O interactions stabilise the molecular structure. In the crystal, C—H⋯O inter­actions result in a chain of mol­ecules running along the b axis.
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spelling pubmed-33793352012-06-20 Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate Anuradha, T. Devaraj, A. Seshadri, P. R. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(15)NO(5), adopts an E conformation with respect to the C=C double bond of the phenyl­acrylate unit. The phenyl ring and methyl acrylate group of the phenyl­acrylate unit are disordered over two sets of sites with site-occupancy ratios of 0.705 (5):0.295 (5) and 0.683 (3):0.317 (3), respectively. The mean plane through the benzene ring of the phenyl acrylate makes dihedral angles of 88.4 (8) (major component) and 86.7 (8)° (minor component) with the nitro­phen­oxy ring; the dihedral angle between the two components is 3.64 (6)°. Intra­molecular C—H⋯O interactions stabilise the molecular structure. In the crystal, C—H⋯O inter­actions result in a chain of mol­ecules running along the b axis. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379335/ /pubmed/22719533 http://dx.doi.org/10.1107/S1600536812021009 Text en © Anuradha et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, T.
Devaraj, A.
Seshadri, P. R.
Bakthadoss, M.
Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
title Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
title_full Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
title_fullStr Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
title_full_unstemmed Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
title_short Methyl (E)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
title_sort methyl (e)-2-[(2-nitro­phen­oxy)meth­yl]-3-phenyl­acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379335/
https://www.ncbi.nlm.nih.gov/pubmed/22719533
http://dx.doi.org/10.1107/S1600536812021009
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