syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate

The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy­droxy and dichloro­methyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C—Cl distances are in the range 1.759 (4)–1.783 (3) Å. Solvent channels parallel to the b axis a...

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Detalles Bibliográficos
Autores principales: Morrison, Gregory W., Fronczek, Frank R., Watkins, Steven F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379341/
https://www.ncbi.nlm.nih.gov/pubmed/22719539
http://dx.doi.org/10.1107/S1600536812020703
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author Morrison, Gregory W.
Fronczek, Frank R.
Watkins, Steven F.
author_facet Morrison, Gregory W.
Fronczek, Frank R.
Watkins, Steven F.
author_sort Morrison, Gregory W.
collection PubMed
description The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy­droxy and dichloro­methyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C—Cl distances are in the range 1.759 (4)–1.783 (3) Å. Solvent channels parallel to the b axis appear to be partially occupied by highly disordered dichloro­methane solvent mol­ecules, the contribution of which were removed from the refinement with the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. Only one of the OH groups forms a hydrogen bond, which is inter­molecular to another OH group, forming centrosymmetric dimers in the crystal.
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spelling pubmed-33793412012-06-20 syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate Morrison, Gregory W. Fronczek, Frank R. Watkins, Steven F. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(18)Cl(6)O(3)·0.82CH(2)Cl(2), consists of a slightly cup-shaped seven-ring truxene nucleus with hy­droxy and dichloro­methyl substituents at stereocenters 5R/S, 10R/S and 15R/S. C—Cl distances are in the range 1.759 (4)–1.783 (3) Å. Solvent channels parallel to the b axis appear to be partially occupied by highly disordered dichloro­methane solvent mol­ecules, the contribution of which were removed from the refinement with the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. Only one of the OH groups forms a hydrogen bond, which is inter­molecular to another OH group, forming centrosymmetric dimers in the crystal. International Union of Crystallography 2012-05-16 /pmc/articles/PMC3379341/ /pubmed/22719539 http://dx.doi.org/10.1107/S1600536812020703 Text en © Morrison et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Morrison, Gregory W.
Fronczek, Frank R.
Watkins, Steven F.
syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
title syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
title_full syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
title_fullStr syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
title_full_unstemmed syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
title_short syn-5,10,15-Tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5H-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
title_sort syn-5,10,15-tris(dichloro­meth­yl)-5,10,15-trihy­droxy-5h-diindeno­[1,2-a:1′,2′-c]fluorene dichloro­methane 0.82-solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379341/
https://www.ncbi.nlm.nih.gov/pubmed/22719539
http://dx.doi.org/10.1107/S1600536812020703
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AT fronczekfrankr syn51015trisdichloromethyl51015trihydroxy5hdiindeno12a12cfluorenedichloromethane082solvate
AT watkinsstevenf syn51015trisdichloromethyl51015trihydroxy5hdiindeno12a12cfluorenedichloromethane082solvate

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