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O-Propyl N-phenylthiocarbamate
Two independent molecules comprise the asymmetric unit in the title thiocarbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C—C—C—O torsion angles = −66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379354/ https://www.ncbi.nlm.nih.gov/pubmed/22719552 http://dx.doi.org/10.1107/S160053681202140X |
Sumario: | Two independent molecules comprise the asymmetric unit in the title thiocarbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C—C—C—O torsion angles = −66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)—N—C(ph)—C(ph) = −146.20 (12) and −144.15 (12)°, respectively; q = quaternary and ph = phenyl]. The independent molecules are linked into a dimeric aggregate by N—H⋯S hydrogen bonds and an eight-membered thioamide {⋯H—N—C=S}(2) synthon. |
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