O-Propyl N-phenyl­thio­carbamate

Two independent mol­ecules comprise the asymmetric unit in the title thio­carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C—C—C—O torsion angles = −66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the c...

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Autores principales: Sudkaow, Panyapon, Yeo, Chien Ing, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379354/
https://www.ncbi.nlm.nih.gov/pubmed/22719552
http://dx.doi.org/10.1107/S160053681202140X
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author Sudkaow, Panyapon
Yeo, Chien Ing
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Sudkaow, Panyapon
Yeo, Chien Ing
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Sudkaow, Panyapon
collection PubMed
description Two independent mol­ecules comprise the asymmetric unit in the title thio­carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C—C—C—O torsion angles = −66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)—N—C(ph)—C(ph) = −146.20 (12) and −144.15 (12)°, respectively; q = quaternary and ph = phen­yl]. The independent mol­ecules are linked into a dimeric aggregate by N—H⋯S hydrogen bonds and an eight-membered thio­amide {⋯H—N—C=S}(2) synthon.
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spelling pubmed-33793542012-06-20 O-Propyl N-phenyl­thio­carbamate Sudkaow, Panyapon Yeo, Chien Ing Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers Two independent mol­ecules comprise the asymmetric unit in the title thio­carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C—C—C—O torsion angles = −66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)—N—C(ph)—C(ph) = −146.20 (12) and −144.15 (12)°, respectively; q = quaternary and ph = phen­yl]. The independent mol­ecules are linked into a dimeric aggregate by N—H⋯S hydrogen bonds and an eight-membered thio­amide {⋯H—N—C=S}(2) synthon. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379354/ /pubmed/22719552 http://dx.doi.org/10.1107/S160053681202140X Text en © Sudkaow et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sudkaow, Panyapon
Yeo, Chien Ing
Ng, Seik Weng
Tiekink, Edward R. T.
O-Propyl N-phenyl­thio­carbamate
title O-Propyl N-phenyl­thio­carbamate
title_full O-Propyl N-phenyl­thio­carbamate
title_fullStr O-Propyl N-phenyl­thio­carbamate
title_full_unstemmed O-Propyl N-phenyl­thio­carbamate
title_short O-Propyl N-phenyl­thio­carbamate
title_sort o-propyl n-phenyl­thio­carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379354/
https://www.ncbi.nlm.nih.gov/pubmed/22719552
http://dx.doi.org/10.1107/S160053681202140X
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AT yeochiening opropylnphenylthiocarbamate
AT ngseikweng opropylnphenylthiocarbamate
AT tiekinkedwardrt opropylnphenylthiocarbamate

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