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5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole
The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent molecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each molecule, there is a twist in the link between the approximately syn carbonyl and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379355/ https://www.ncbi.nlm.nih.gov/pubmed/22719553 http://dx.doi.org/10.1107/S1600536812020399 |
Sumario: | The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent molecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each molecule, there is a twist in the link between the approximately syn carbonyl and amine groups [the N—C—C—O torsion angles range from 19.73 (19) to −21.2 (2)°]. Each molecule has a bent shape quantified in terms of the dihedral angle between the indole and indole fused-ring systems [range = 45.69 (5)–47.91 (5)°]. In the crystal, the A and B molecules form dimeric aggregates via ten-membered {⋯HNC(2)O}(2) synthons, while the C molecules self-associate similarly but about a centre of inversion. |
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