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5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole

The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent mol­ecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each mol­ecule, there is a twist in the link between the approximately syn carbonyl and...

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Autores principales: Attia, Mohamed I., El-Brollosy, Nasser R., El-Emam, Ali A., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379355/
https://www.ncbi.nlm.nih.gov/pubmed/22719553
http://dx.doi.org/10.1107/S1600536812020399
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author Attia, Mohamed I.
El-Brollosy, Nasser R.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Attia, Mohamed I.
El-Brollosy, Nasser R.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Attia, Mohamed I.
collection PubMed
description The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent mol­ecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each mol­ecule, there is a twist in the link between the approximately syn carbonyl and amine groups [the N—C—C—O torsion angles range from 19.73 (19) to −21.2 (2)°]. Each mol­ecule has a bent shape quanti­fied in terms of the dihedral angle between the indole and indole fused-ring systems [range = 45.69 (5)–47.91 (5)°]. In the crystal, the A and B mol­ecules form dimeric aggregates via ten-membered {⋯HNC(2)O}(2) synthons, while the C mol­ecules self-associate similarly but about a centre of inversion.
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spelling pubmed-33793552012-06-20 5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole Attia, Mohamed I. El-Brollosy, Nasser R. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent mol­ecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each mol­ecule, there is a twist in the link between the approximately syn carbonyl and amine groups [the N—C—C—O torsion angles range from 19.73 (19) to −21.2 (2)°]. Each mol­ecule has a bent shape quanti­fied in terms of the dihedral angle between the indole and indole fused-ring systems [range = 45.69 (5)–47.91 (5)°]. In the crystal, the A and B mol­ecules form dimeric aggregates via ten-membered {⋯HNC(2)O}(2) synthons, while the C mol­ecules self-associate similarly but about a centre of inversion. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379355/ /pubmed/22719553 http://dx.doi.org/10.1107/S1600536812020399 Text en © Attia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Attia, Mohamed I.
El-Brollosy, Nasser R.
El-Emam, Ali A.
Ng, Seik Weng
Tiekink, Edward R. T.
5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole
title 5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole
title_full 5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole
title_fullStr 5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole
title_full_unstemmed 5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole
title_short 5-Meth­oxy-2-[(5-meth­oxy-1H-indol-1-yl)carbon­yl]-1H-indole
title_sort 5-meth­oxy-2-[(5-meth­oxy-1h-indol-1-yl)carbon­yl]-1h-indole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379355/
https://www.ncbi.nlm.nih.gov/pubmed/22719553
http://dx.doi.org/10.1107/S1600536812020399
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