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5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole
The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent molecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each molecule, there is a twist in the link between the approximately syn carbonyl and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379355/ https://www.ncbi.nlm.nih.gov/pubmed/22719553 http://dx.doi.org/10.1107/S1600536812020399 |
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author | Attia, Mohamed I. El-Brollosy, Nasser R. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Attia, Mohamed I. El-Brollosy, Nasser R. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Attia, Mohamed I. |
collection | PubMed |
description | The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent molecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each molecule, there is a twist in the link between the approximately syn carbonyl and amine groups [the N—C—C—O torsion angles range from 19.73 (19) to −21.2 (2)°]. Each molecule has a bent shape quantified in terms of the dihedral angle between the indole and indole fused-ring systems [range = 45.69 (5)–47.91 (5)°]. In the crystal, the A and B molecules form dimeric aggregates via ten-membered {⋯HNC(2)O}(2) synthons, while the C molecules self-associate similarly but about a centre of inversion. |
format | Online Article Text |
id | pubmed-3379355 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33793552012-06-20 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole Attia, Mohamed I. El-Brollosy, Nasser R. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(16)N(2)O(3), comprises three independent molecules (A, B and C). The inversion-related molecule of A is virtually superimposable upon the other two molecules. In each molecule, there is a twist in the link between the approximately syn carbonyl and amine groups [the N—C—C—O torsion angles range from 19.73 (19) to −21.2 (2)°]. Each molecule has a bent shape quantified in terms of the dihedral angle between the indole and indole fused-ring systems [range = 45.69 (5)–47.91 (5)°]. In the crystal, the A and B molecules form dimeric aggregates via ten-membered {⋯HNC(2)O}(2) synthons, while the C molecules self-associate similarly but about a centre of inversion. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379355/ /pubmed/22719553 http://dx.doi.org/10.1107/S1600536812020399 Text en © Attia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Attia, Mohamed I. El-Brollosy, Nasser R. El-Emam, Ali A. Ng, Seik Weng Tiekink, Edward R. T. 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole |
title | 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole |
title_full | 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole |
title_fullStr | 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole |
title_full_unstemmed | 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole |
title_short | 5-Methoxy-2-[(5-methoxy-1H-indol-1-yl)carbonyl]-1H-indole |
title_sort | 5-methoxy-2-[(5-methoxy-1h-indol-1-yl)carbonyl]-1h-indole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379355/ https://www.ncbi.nlm.nih.gov/pubmed/22719553 http://dx.doi.org/10.1107/S1600536812020399 |
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