5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane

In the mol­ecule of the title compound, C(16)H(20)N(4), the 1,3-diazinane ring adopts a chair conformation and the dihedral angle formed by the pyridine rings is 78.64 (8)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond, forming an S(6) ring motif. In the crysta...

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Detalles Bibliográficos
Autores principales: Warad, Ismail, Alruwaili, Afaf, Al-Resayes, Saud I., Choudhary, M. Iqbal, Yousuf, Sammer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379365/
https://www.ncbi.nlm.nih.gov/pubmed/22719563
http://dx.doi.org/10.1107/S1600536812021629
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author Warad, Ismail
Alruwaili, Afaf
Al-Resayes, Saud I.
Choudhary, M. Iqbal
Yousuf, Sammer
author_facet Warad, Ismail
Alruwaili, Afaf
Al-Resayes, Saud I.
Choudhary, M. Iqbal
Yousuf, Sammer
author_sort Warad, Ismail
collection PubMed
description In the mol­ecule of the title compound, C(16)H(20)N(4), the 1,3-diazinane ring adopts a chair conformation and the dihedral angle formed by the pyridine rings is 78.64 (8)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond, forming an S(6) ring motif. In the crystal, centrosymmetrically related mol­ecules are linked into dimers by pairs of N—H⋯N hydrogen bonds, generating rings of R (2) (2)(10) graph-set motif.
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spelling pubmed-33793652012-06-20 5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane Warad, Ismail Alruwaili, Afaf Al-Resayes, Saud I. Choudhary, M. Iqbal Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(16)H(20)N(4), the 1,3-diazinane ring adopts a chair conformation and the dihedral angle formed by the pyridine rings is 78.64 (8)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond, forming an S(6) ring motif. In the crystal, centrosymmetrically related mol­ecules are linked into dimers by pairs of N—H⋯N hydrogen bonds, generating rings of R (2) (2)(10) graph-set motif. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379365/ /pubmed/22719563 http://dx.doi.org/10.1107/S1600536812021629 Text en © Warad et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Warad, Ismail
Alruwaili, Afaf
Al-Resayes, Saud I.
Choudhary, M. Iqbal
Yousuf, Sammer
5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
title 5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
title_full 5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
title_fullStr 5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
title_full_unstemmed 5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
title_short 5,5-Dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
title_sort 5,5-dimethyl-2,2-bis­(pyridin-2-yl)-1,3-diazinane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379365/
https://www.ncbi.nlm.nih.gov/pubmed/22719563
http://dx.doi.org/10.1107/S1600536812021629
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AT choudharymiqbal 55dimethyl22bispyridin2yl13diazinane
AT yousufsammer 55dimethyl22bispyridin2yl13diazinane

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