rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione

In the title compound, C(16)H(13)ClFN(3)O(2)S, the dihedral angle between the benzene rings is 4.47 (3)°. The conformation of the thia­zine ring is a half-chair and the Cl atom is in an axial orientation. In the crystal, mol­ecules are linked by C—H⋯F inter­actions, generating C(12) chains propagati...

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Detalles Bibliográficos
Autores principales: Shafiq, Muhammad, Tahir, M. Nawaz, Khan, Islam Ullah, Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379366/
https://www.ncbi.nlm.nih.gov/pubmed/22719564
http://dx.doi.org/10.1107/S1600536812021654
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author Shafiq, Muhammad
Tahir, M. Nawaz
Khan, Islam Ullah
Ahmad, Saeed
author_facet Shafiq, Muhammad
Tahir, M. Nawaz
Khan, Islam Ullah
Ahmad, Saeed
author_sort Shafiq, Muhammad
collection PubMed
description In the title compound, C(16)H(13)ClFN(3)O(2)S, the dihedral angle between the benzene rings is 4.47 (3)°. The conformation of the thia­zine ring is a half-chair and the Cl atom is in an axial orientation. In the crystal, mol­ecules are linked by C—H⋯F inter­actions, generating C(12) chains propagating in [011]. Aromatic π–π stacking inter­actions [centroid–centroid separations = 3.753 (2) and 3.758 (2) Å] also occur.
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spelling pubmed-33793662012-06-20 rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione Shafiq, Muhammad Tahir, M. Nawaz Khan, Islam Ullah Ahmad, Saeed Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(13)ClFN(3)O(2)S, the dihedral angle between the benzene rings is 4.47 (3)°. The conformation of the thia­zine ring is a half-chair and the Cl atom is in an axial orientation. In the crystal, mol­ecules are linked by C—H⋯F inter­actions, generating C(12) chains propagating in [011]. Aromatic π–π stacking inter­actions [centroid–centroid separations = 3.753 (2) and 3.758 (2) Å] also occur. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379366/ /pubmed/22719564 http://dx.doi.org/10.1107/S1600536812021654 Text en © Shafiq et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Tahir, M. Nawaz
Khan, Islam Ullah
Ahmad, Saeed
rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_full rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_fullStr rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_full_unstemmed rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_short rac-(3S,4Z)-3-Chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_sort rac-(3s,4z)-3-chloro-4-[2-(3-fluoro­benzyl­idene)hydrazinyl­idene]-1-methyl-3,4-dihydro-1h-2λ(6),1-benzothia­zine-2,2-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379366/
https://www.ncbi.nlm.nih.gov/pubmed/22719564
http://dx.doi.org/10.1107/S1600536812021654
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