Cargando…
(Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one
The title compound, C(22)H(22)N(2)OS, exists in a cis conformation with respect to the N=C bond. The cyclohexene ring adopts a distorted sofa conformation. The thiazolidine ring is essentially planar with a maximum deviation of 0.025 (2) Å and forms dihedral angles of 63.50 (7) and 57.52 (6)° with...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379373/ https://www.ncbi.nlm.nih.gov/pubmed/22719571 http://dx.doi.org/10.1107/S1600536812021691 |
| _version_ | 1782236185181028352 |
|---|---|
| author | Ooi, Chin Wei Fun, Hoong-Kun Quah, Ching Kheng Sathishkumar, Murugan Ponnuswamy, Alagusundaram |
| author_facet | Ooi, Chin Wei Fun, Hoong-Kun Quah, Ching Kheng Sathishkumar, Murugan Ponnuswamy, Alagusundaram |
| author_sort | Ooi, Chin Wei |
| collection | PubMed |
| description | The title compound, C(22)H(22)N(2)OS, exists in a cis conformation with respect to the N=C bond. The cyclohexene ring adopts a distorted sofa conformation. The thiazolidine ring is essentially planar with a maximum deviation of 0.025 (2) Å and forms dihedral angles of 63.50 (7) and 57.52 (6)° with the benzene rings. In the crystal, molecules are linked by C—H⋯O and C—H⋯N hydrogen bonds, generating R (2) (2)(8) ring motifs, and forming infinite chains along the c axis. The crystal is further consolidated by C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3379373 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33793732012-06-20 (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one Ooi, Chin Wei Fun, Hoong-Kun Quah, Ching Kheng Sathishkumar, Murugan Ponnuswamy, Alagusundaram Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(22)N(2)OS, exists in a cis conformation with respect to the N=C bond. The cyclohexene ring adopts a distorted sofa conformation. The thiazolidine ring is essentially planar with a maximum deviation of 0.025 (2) Å and forms dihedral angles of 63.50 (7) and 57.52 (6)° with the benzene rings. In the crystal, molecules are linked by C—H⋯O and C—H⋯N hydrogen bonds, generating R (2) (2)(8) ring motifs, and forming infinite chains along the c axis. The crystal is further consolidated by C—H⋯π interactions. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379373/ /pubmed/22719571 http://dx.doi.org/10.1107/S1600536812021691 Text en © Ooi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Ooi, Chin Wei Fun, Hoong-Kun Quah, Ching Kheng Sathishkumar, Murugan Ponnuswamy, Alagusundaram (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| title | (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| title_full | (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| title_fullStr | (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| title_full_unstemmed | (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| title_short | (Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| title_sort | (z)-3-(4-methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379373/ https://www.ncbi.nlm.nih.gov/pubmed/22719571 http://dx.doi.org/10.1107/S1600536812021691 |
| work_keys_str_mv | AT ooichinwei z34methylphenyl22phenylcyclohex2en1ylimino13thiazolidin4one AT funhoongkun z34methylphenyl22phenylcyclohex2en1ylimino13thiazolidin4one AT quahchingkheng z34methylphenyl22phenylcyclohex2en1ylimino13thiazolidin4one AT sathishkumarmurugan z34methylphenyl22phenylcyclohex2en1ylimino13thiazolidin4one AT ponnuswamyalagusundaram z34methylphenyl22phenylcyclohex2en1ylimino13thiazolidin4one |