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1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea
In the title compound, C(21)H(23)N(5)O(2), the conformation about the imine bond [1.287 (3) Å] is E. Overall, the molecule has a disk shape, the dihedral angles between the imidazole ring and the methoxyphenyl and methylphenyl rings being 49.42 (13) and 42.62 (13)°, respectively; the dihedral an...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379375/ https://www.ncbi.nlm.nih.gov/pubmed/22719573 http://dx.doi.org/10.1107/S1600536812021903 |
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author | Attia, Mohamed I. Aboul-Enein, Mohamed N. El-Brollosy, Nasser R. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Attia, Mohamed I. Aboul-Enein, Mohamed N. El-Brollosy, Nasser R. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Attia, Mohamed I. |
collection | PubMed |
description | In the title compound, C(21)H(23)N(5)O(2), the conformation about the imine bond [1.287 (3) Å] is E. Overall, the molecule has a disk shape, the dihedral angles between the imidazole ring and the methoxyphenyl and methylphenyl rings being 49.42 (13) and 42.62 (13)°, respectively; the dihedral angle between the benzene rings is 20.11 (11)°. In the urea moiety, the N—H atoms are anti to each other and one of these forms an intramolecular N—H⋯N hydrogen bond. In the crystal, centrosymmetric dimers are formed via N—H⋯N(imidazole) hydrogen bonds, which are connected into a three-dimensional architecture by C—H⋯O(carbonyl) and (methylene)C—H⋯π interactions. The crystal studied was a non-merohedral twin with a minor component of 48.3 (1)%. |
format | Online Article Text |
id | pubmed-3379375 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33793752012-06-20 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea Attia, Mohamed I. Aboul-Enein, Mohamed N. El-Brollosy, Nasser R. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(23)N(5)O(2), the conformation about the imine bond [1.287 (3) Å] is E. Overall, the molecule has a disk shape, the dihedral angles between the imidazole ring and the methoxyphenyl and methylphenyl rings being 49.42 (13) and 42.62 (13)°, respectively; the dihedral angle between the benzene rings is 20.11 (11)°. In the urea moiety, the N—H atoms are anti to each other and one of these forms an intramolecular N—H⋯N hydrogen bond. In the crystal, centrosymmetric dimers are formed via N—H⋯N(imidazole) hydrogen bonds, which are connected into a three-dimensional architecture by C—H⋯O(carbonyl) and (methylene)C—H⋯π interactions. The crystal studied was a non-merohedral twin with a minor component of 48.3 (1)%. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379375/ /pubmed/22719573 http://dx.doi.org/10.1107/S1600536812021903 Text en © Attia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Attia, Mohamed I. Aboul-Enein, Mohamed N. El-Brollosy, Nasser R. Ng, Seik Weng Tiekink, Edward R. T. 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
title | 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
title_full | 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
title_fullStr | 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
title_full_unstemmed | 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
title_short | 1-{(E)-[3-(1H-Imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
title_sort | 1-{(e)-[3-(1h-imidazol-1-yl)-1-(4-methoxyphenyl)propylidene]amino}-3-(2-methylphenyl)urea |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379375/ https://www.ncbi.nlm.nih.gov/pubmed/22719573 http://dx.doi.org/10.1107/S1600536812021903 |
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