1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea

The asymmetric unit of the title compound, C(11)H(12)ClN(3)O(3)S, contains two independent mol­ecules with different conformations in which the benzene ring and the thio­urea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thio­amide group is involved in bifurcated N—H...

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Detalles Bibliográficos
Autores principales: Ngah, Nurziana, Kadir, Maisara, Yamin, Bohari M., Yusof, M. Sukeri M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379376/
https://www.ncbi.nlm.nih.gov/pubmed/22719574
http://dx.doi.org/10.1107/S160053681202168X
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author Ngah, Nurziana
Kadir, Maisara
Yamin, Bohari M.
Yusof, M. Sukeri M.
author_facet Ngah, Nurziana
Kadir, Maisara
Yamin, Bohari M.
Yusof, M. Sukeri M.
author_sort Ngah, Nurziana
collection PubMed
description The asymmetric unit of the title compound, C(11)H(12)ClN(3)O(3)S, contains two independent mol­ecules with different conformations in which the benzene ring and the thio­urea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thio­amide group is involved in bifurcated N—H⋯O intra- and inter­molecular hydrogen bonding; the latter inter­action links the independent mol­ecules into a dimer. In the crystal, N—H⋯S inter­actions link the mol­ecules into chains propagating along the c axis.
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spelling pubmed-33793762012-06-20 1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea Ngah, Nurziana Kadir, Maisara Yamin, Bohari M. Yusof, M. Sukeri M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(12)ClN(3)O(3)S, contains two independent mol­ecules with different conformations in which the benzene ring and the thio­urea fragment form dihedral angles of 87.28 (12) and 66.44 (10)°. The O atom of the thio­amide group is involved in bifurcated N—H⋯O intra- and inter­molecular hydrogen bonding; the latter inter­action links the independent mol­ecules into a dimer. In the crystal, N—H⋯S inter­actions link the mol­ecules into chains propagating along the c axis. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379376/ /pubmed/22719574 http://dx.doi.org/10.1107/S160053681202168X Text en © Ngah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ngah, Nurziana
Kadir, Maisara
Yamin, Bohari M.
Yusof, M. Sukeri M.
1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
title 1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
title_full 1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
title_fullStr 1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
title_full_unstemmed 1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
title_short 1-(4-Chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
title_sort 1-(4-chloro­butano­yl)-3-(2-nitro­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379376/
https://www.ncbi.nlm.nih.gov/pubmed/22719574
http://dx.doi.org/10.1107/S160053681202168X
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AT kadirmaisara 14chlorobutanoyl32nitrophenylthiourea
AT yaminboharim 14chlorobutanoyl32nitrophenylthiourea
AT yusofmsukerim 14chlorobutanoyl32nitrophenylthiourea

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