3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide

The reaction of 3,3,3-tris­(dimethyl­amino)-1-phenyl­prop-1-yne with bromine in pentane yields the title compound, C(13)H(17)N(2) (+)·Br(−). The acetyl­enic bond distance [1.197 (2) Å] is consistent with a C C triple bond. The amidinium C=N bonds [1.325 (2) and 1.330 (2) Å] have double-bond characte...

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379386/
https://www.ncbi.nlm.nih.gov/pubmed/22719584
http://dx.doi.org/10.1107/S1600536812021873
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author Tiritiris, Ioannis
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description The reaction of 3,3,3-tris­(dimethyl­amino)-1-phenyl­prop-1-yne with bromine in pentane yields the title compound, C(13)H(17)N(2) (+)·Br(−). The acetyl­enic bond distance [1.197 (2) Å] is consistent with a C C triple bond. The amidinium C=N bonds [1.325 (2) and 1.330 (2) Å] have double-bond character and the positive charge is delocalized between the two dimethyl­amino groups.
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spelling pubmed-33793862012-06-20 3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide Tiritiris, Ioannis Kantlehner, Willi Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 3,3,3-tris­(dimethyl­amino)-1-phenyl­prop-1-yne with bromine in pentane yields the title compound, C(13)H(17)N(2) (+)·Br(−). The acetyl­enic bond distance [1.197 (2) Å] is consistent with a C C triple bond. The amidinium C=N bonds [1.325 (2) and 1.330 (2) Å] have double-bond character and the positive charge is delocalized between the two dimethyl­amino groups. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379386/ /pubmed/22719584 http://dx.doi.org/10.1107/S1600536812021873 Text en © Tiritiris and Kantlehner 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
Kantlehner, Willi
3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
title 3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
title_full 3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
title_fullStr 3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
title_full_unstemmed 3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
title_short 3-Phenyl-N,N,N′,N′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
title_sort 3-phenyl-n,n,n′,n′-tetra­methyl-1-ethyne-1-carboximidamidium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379386/
https://www.ncbi.nlm.nih.gov/pubmed/22719584
http://dx.doi.org/10.1107/S1600536812021873
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