9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate

The title compound, C(17)H(12)N(2)O·H(2)O, was synthesized by the reaction of 4,5-diaza­fluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH(4)Cl solution), and crystallizes with two organic mol­ecules and two water mol­ecules in the asymmetric unit...

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Detalles Bibliográficos
Autores principales: Yin, Guo-Jie, Yang, Gang-Bin, Wang, Shi-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379391/
https://www.ncbi.nlm.nih.gov/pubmed/22719589
http://dx.doi.org/10.1107/S1600536812021940
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author Yin, Guo-Jie
Yang, Gang-Bin
Wang, Shi-Min
author_facet Yin, Guo-Jie
Yang, Gang-Bin
Wang, Shi-Min
author_sort Yin, Guo-Jie
collection PubMed
description The title compound, C(17)H(12)N(2)O·H(2)O, was synthesized by the reaction of 4,5-diaza­fluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH(4)Cl solution), and crystallizes with two organic mol­ecules and two water mol­ecules in the asymmetric unit. The 4,5-diaza­fluorene fragment is approximately planar, with r.m.s. deviations of 0.0448 and 0.0198 Å in the two mol­ecules. The dihedral angles between the 4,5-diaza­fluorene planes and the phenyl ring are 80.49 (6) and 76.57 (7)°. The crystal packing features O—H⋯N and O—H⋯O hydrogen bonds involving the bridging solvent water mol­ecules, which link the mol­ecules into a three-dimensional network.
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spelling pubmed-33793912012-06-20 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate Yin, Guo-Jie Yang, Gang-Bin Wang, Shi-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(12)N(2)O·H(2)O, was synthesized by the reaction of 4,5-diaza­fluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH(4)Cl solution), and crystallizes with two organic mol­ecules and two water mol­ecules in the asymmetric unit. The 4,5-diaza­fluorene fragment is approximately planar, with r.m.s. deviations of 0.0448 and 0.0198 Å in the two mol­ecules. The dihedral angles between the 4,5-diaza­fluorene planes and the phenyl ring are 80.49 (6) and 76.57 (7)°. The crystal packing features O—H⋯N and O—H⋯O hydrogen bonds involving the bridging solvent water mol­ecules, which link the mol­ecules into a three-dimensional network. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379391/ /pubmed/22719589 http://dx.doi.org/10.1107/S1600536812021940 Text en © Yin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yin, Guo-Jie
Yang, Gang-Bin
Wang, Shi-Min
9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
title 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
title_full 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
title_fullStr 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
title_full_unstemmed 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
title_short 9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate
title_sort 9-phenyl-4,5-diaza-9h-fluoren-9-ol monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379391/
https://www.ncbi.nlm.nih.gov/pubmed/22719589
http://dx.doi.org/10.1107/S1600536812021940
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