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3-Ethenyl-1-(4-methyl­phenyl­sulfon­yl)-1H-indole

Two independent but very similar mol­ecules comprise the asymmetric unit of the title compound, C(17)H(15)NO(2)S. The mol­ecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e....

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Wulf, Glaudeston D., Stefani, Hélio A., Vasconcelos, Stanley N. S., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379403/
https://www.ncbi.nlm.nih.gov/pubmed/22719601
http://dx.doi.org/10.1107/S1600536812021526
Descripción
Sumario:Two independent but very similar mol­ecules comprise the asymmetric unit of the title compound, C(17)H(15)NO(2)S. The mol­ecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the ring to which it is connected [C—C—C—C torsion angles = −173.7 (4) and −171.7 (4)°, respectively]. Supra­molecular arrays parallel to (-124) stabilized by C—H⋯O and C—H⋯π inter­actions feature in the crystal packing.