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3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole
Two independent but very similar molecules comprise the asymmetric unit of the title compound, C(17)H(15)NO(2)S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e....
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379403/ https://www.ncbi.nlm.nih.gov/pubmed/22719601 http://dx.doi.org/10.1107/S1600536812021526 |
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| author | Zukerman-Schpector, Julio Wulf, Glaudeston D. Stefani, Hélio A. Vasconcelos, Stanley N. S. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Zukerman-Schpector, Julio Wulf, Glaudeston D. Stefani, Hélio A. Vasconcelos, Stanley N. S. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Zukerman-Schpector, Julio |
| collection | PubMed |
| description | Two independent but very similar molecules comprise the asymmetric unit of the title compound, C(17)H(15)NO(2)S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the ring to which it is connected [C—C—C—C torsion angles = −173.7 (4) and −171.7 (4)°, respectively]. Supramolecular arrays parallel to (-124) stabilized by C—H⋯O and C—H⋯π interactions feature in the crystal packing. |
| format | Online Article Text |
| id | pubmed-3379403 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33794032012-06-20 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole Zukerman-Schpector, Julio Wulf, Glaudeston D. Stefani, Hélio A. Vasconcelos, Stanley N. S. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers Two independent but very similar molecules comprise the asymmetric unit of the title compound, C(17)H(15)NO(2)S. The molecules have L-shapes with the dihedral angles between the fused-ring system (r.m.s. deviations = 0.036 and 0.019 Å, respectively) and the benzene ring being almost the same, i.e. 82.98 (12) and 84.46 (13)°, respectively. The terminal ethenyl group is almost coplanar with the ring to which it is connected [C—C—C—C torsion angles = −173.7 (4) and −171.7 (4)°, respectively]. Supramolecular arrays parallel to (-124) stabilized by C—H⋯O and C—H⋯π interactions feature in the crystal packing. International Union of Crystallography 2012-05-19 /pmc/articles/PMC3379403/ /pubmed/22719601 http://dx.doi.org/10.1107/S1600536812021526 Text en © Zukerman-Schpector et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Zukerman-Schpector, Julio Wulf, Glaudeston D. Stefani, Hélio A. Vasconcelos, Stanley N. S. Ng, Seik Weng Tiekink, Edward R. T. 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole |
| title | 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole |
| title_full | 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole |
| title_fullStr | 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole |
| title_full_unstemmed | 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole |
| title_short | 3-Ethenyl-1-(4-methylphenylsulfonyl)-1H-indole |
| title_sort | 3-ethenyl-1-(4-methylphenylsulfonyl)-1h-indole |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379403/ https://www.ncbi.nlm.nih.gov/pubmed/22719601 http://dx.doi.org/10.1107/S1600536812021526 |
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