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N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide

The asymmetric unit of the title compound, C(8)H(14)N(6)O(2), contains two independent mol­ecules. In one mol­ecule, the amide-substituted N atoms of the tetra­zine ring deviate from the plane [maximum deviation = 0.028 (1) Å] through the four other atoms in the ring by 0.350 (2) and 0.344 (2) Å, fo...

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Detalles Bibliográficos
Autores principales: Sun, Na-Bo, Rao, Guo-Wu, Shen, Qun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379411/
https://www.ncbi.nlm.nih.gov/pubmed/22719609
http://dx.doi.org/10.1107/S1600536812022519
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author Sun, Na-Bo
Rao, Guo-Wu
Shen, Qun
author_facet Sun, Na-Bo
Rao, Guo-Wu
Shen, Qun
author_sort Sun, Na-Bo
collection PubMed
description The asymmetric unit of the title compound, C(8)H(14)N(6)O(2), contains two independent mol­ecules. In one mol­ecule, the amide-substituted N atoms of the tetra­zine ring deviate from the plane [maximum deviation = 0.028 (1) Å] through the four other atoms in the ring by 0.350 (2) and 0.344 (2) Å, forming a boat conformation, and the mean planes of the two carboxamide groups form dihedral angles of 10.46 (13) and 20.41 (12)° with the four approximtely planar atoms in the tetra­zine ring. In the other mol­ecule, the amide-substituted N atoms of the tetra­zine ring deviate from the plane [maximum deviation = 0.033 (1) Å] through the four other atoms in the ring by 0.324 (2) and 0.307 (2) Å, forming a boat conformation, and the mean planes of the two carboxamide groups form dihedral angles of 14.66 (11) and 17.08 (10)° with the four approximately planar atoms of the tetra­zine ring. In the crystal, N—H⋯O hydrogen bonds connect mol­ecules to form a two-dimensional network parallel to (1-1-1). Intra­molecular N—H⋯N hydrogen bonds are observed.
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spelling pubmed-33794112012-06-20 N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide Sun, Na-Bo Rao, Guo-Wu Shen, Qun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(14)N(6)O(2), contains two independent mol­ecules. In one mol­ecule, the amide-substituted N atoms of the tetra­zine ring deviate from the plane [maximum deviation = 0.028 (1) Å] through the four other atoms in the ring by 0.350 (2) and 0.344 (2) Å, forming a boat conformation, and the mean planes of the two carboxamide groups form dihedral angles of 10.46 (13) and 20.41 (12)° with the four approximtely planar atoms in the tetra­zine ring. In the other mol­ecule, the amide-substituted N atoms of the tetra­zine ring deviate from the plane [maximum deviation = 0.033 (1) Å] through the four other atoms in the ring by 0.324 (2) and 0.307 (2) Å, forming a boat conformation, and the mean planes of the two carboxamide groups form dihedral angles of 14.66 (11) and 17.08 (10)° with the four approximately planar atoms of the tetra­zine ring. In the crystal, N—H⋯O hydrogen bonds connect mol­ecules to form a two-dimensional network parallel to (1-1-1). Intra­molecular N—H⋯N hydrogen bonds are observed. International Union of Crystallography 2012-05-23 /pmc/articles/PMC3379411/ /pubmed/22719609 http://dx.doi.org/10.1107/S1600536812022519 Text en © Sun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Na-Bo
Rao, Guo-Wu
Shen, Qun
N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
title N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
title_full N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
title_fullStr N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
title_full_unstemmed N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
title_short N (1),N (4),3,6-Tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
title_sort n (1),n (4),3,6-tetra­methyl-1,2,4,5-tetra­zine-1,4-dicarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379411/
https://www.ncbi.nlm.nih.gov/pubmed/22719609
http://dx.doi.org/10.1107/S1600536812022519
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