1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate

In the title compound, C(27)H(37)N(2) (+)·Cl(−)·2CH(2)Cl(2), the cation and the anion are each located on a crystallographic mirror plane. Both of the dichloro­methane solvent mol­ecules show a disorder across a mirror plane over two equally occupied positions. Additionally, one isopropyl group is a...

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Detalles Bibliográficos
Autores principales: Berger, Matthias, Auner, Norbert, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379413/
https://www.ncbi.nlm.nih.gov/pubmed/22719611
http://dx.doi.org/10.1107/S1600536812022234
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author Berger, Matthias
Auner, Norbert
Bolte, Michael
author_facet Berger, Matthias
Auner, Norbert
Bolte, Michael
author_sort Berger, Matthias
collection PubMed
description In the title compound, C(27)H(37)N(2) (+)·Cl(−)·2CH(2)Cl(2), the cation and the anion are each located on a crystallographic mirror plane. Both of the dichloro­methane solvent mol­ecules show a disorder across a mirror plane over two equally occupied positions. Additionally, one isopropyl group is also disordered. In the crystal, the cations are connected to the chloride ions via C—H⋯Cl hydrogen bonds.
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spelling pubmed-33794132012-06-20 1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate Berger, Matthias Auner, Norbert Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(37)N(2) (+)·Cl(−)·2CH(2)Cl(2), the cation and the anion are each located on a crystallographic mirror plane. Both of the dichloro­methane solvent mol­ecules show a disorder across a mirror plane over two equally occupied positions. Additionally, one isopropyl group is also disordered. In the crystal, the cations are connected to the chloride ions via C—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-05-23 /pmc/articles/PMC3379413/ /pubmed/22719611 http://dx.doi.org/10.1107/S1600536812022234 Text en © Berger et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Berger, Matthias
Auner, Norbert
Bolte, Michael
1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate
title 1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate
title_full 1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate
title_fullStr 1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate
title_full_unstemmed 1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate
title_short 1,3-Bis(2,6-diisopropyl­phen­yl)-1H-imidazol-3-ium chloride dichloro­methane disolvate
title_sort 1,3-bis(2,6-diisopropyl­phen­yl)-1h-imidazol-3-ium chloride dichloro­methane disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379413/
https://www.ncbi.nlm.nih.gov/pubmed/22719611
http://dx.doi.org/10.1107/S1600536812022234
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