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1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea

In the title compound, C(20)H(21)N(5)O, the conformation about the imine bond [1.289 (3) Å] is E. Overall, the mol­ecule is disk-shaped with the imidazole ring located above the remainder of the mol­ecule and with the dihedral angles of 10.97 (15) and 12.11 (15)°, respectively, between the imidazole...

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Autores principales: Attia, Mohamed I., Aboul-Enein, Mohamed N., El-Brollosy, Nasser R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379417/
https://www.ncbi.nlm.nih.gov/pubmed/22719615
http://dx.doi.org/10.1107/S1600536812022659
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author Attia, Mohamed I.
Aboul-Enein, Mohamed N.
El-Brollosy, Nasser R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Attia, Mohamed I.
Aboul-Enein, Mohamed N.
El-Brollosy, Nasser R.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Attia, Mohamed I.
collection PubMed
description In the title compound, C(20)H(21)N(5)O, the conformation about the imine bond [1.289 (3) Å] is E. Overall, the mol­ecule is disk-shaped with the imidazole ring located above the remainder of the mol­ecule and with the dihedral angles of 10.97 (15) and 12.11 (15)°, respectively, between the imidazole ring and the phenyl and methyl­benzene rings; the dihedral angle between the aromatic rings is 8.17 (14)°. Within the urea unit, the N—H atoms are anti to each other and one of the N—H atoms forms an intra­molecular N—H⋯N hydrogen bond. Helical supra­molecular chains along [001] are formed via N—H⋯N(imidazole) hydrogen bonds in the crystal structure. These are connected into a three-dimensional architecture by C—H⋯O(carbon­yl) and C—H⋯π inter­actions.
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spelling pubmed-33794172012-06-20 1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea Attia, Mohamed I. Aboul-Enein, Mohamed N. El-Brollosy, Nasser R. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)N(5)O, the conformation about the imine bond [1.289 (3) Å] is E. Overall, the mol­ecule is disk-shaped with the imidazole ring located above the remainder of the mol­ecule and with the dihedral angles of 10.97 (15) and 12.11 (15)°, respectively, between the imidazole ring and the phenyl and methyl­benzene rings; the dihedral angle between the aromatic rings is 8.17 (14)°. Within the urea unit, the N—H atoms are anti to each other and one of the N—H atoms forms an intra­molecular N—H⋯N hydrogen bond. Helical supra­molecular chains along [001] are formed via N—H⋯N(imidazole) hydrogen bonds in the crystal structure. These are connected into a three-dimensional architecture by C—H⋯O(carbon­yl) and C—H⋯π inter­actions. International Union of Crystallography 2012-05-23 /pmc/articles/PMC3379417/ /pubmed/22719615 http://dx.doi.org/10.1107/S1600536812022659 Text en © Attia et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Attia, Mohamed I.
Aboul-Enein, Mohamed N.
El-Brollosy, Nasser R.
Ng, Seik Weng
Tiekink, Edward R. T.
1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
title 1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
title_full 1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
title_fullStr 1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
title_full_unstemmed 1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
title_short 1-{(E)-[3-(1H-Imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
title_sort 1-{(e)-[3-(1h-imidazol-1-yl)-1-phenyl­propyl­idene]amino}-3-(2-methyl­phen­yl)urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379417/
https://www.ncbi.nlm.nih.gov/pubmed/22719615
http://dx.doi.org/10.1107/S1600536812022659
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